Combustion Equations: Converting kg to kmol & KJ/Kmol to KJ/Kg

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Discussion Overview

The discussion revolves around the conversion of units in combustion equations, specifically the transition between kilograms (kg) and kilomoles (kmol), as well as the conversion of enthalpy values from kilojoules per kilomole (KJ/kmol) to kilojoules per kilogram (KJ/kg). The context includes theoretical understanding and practical applications related to combustion reactions.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant inquires whether reaction equations are typically presented in kg or kmol, expressing uncertainty when only the reaction equation is available.
  • Another participant suggests that chemical combustion equations are given in moles and recommends balancing them for stoichiometric calculations, followed by converting to gravimetric weight.
  • A participant seeks clarification on how to convert enthalpy values from KJ/kmol to KJ/kg, indicating that their previous attempts using mols multiplied by molecular weight did not yield the desired results.
  • Additional recommendations for literature on combustion are provided, emphasizing the importance of being cautious with reference values from different sources.

Areas of Agreement / Disagreement

Participants generally agree that combustion equations are presented in moles and that conversion to gravimetric weight is necessary. However, the method for converting enthalpy values remains unresolved, with differing approaches suggested without consensus on the correct method.

Contextual Notes

There are limitations regarding the assumptions made about the availability of reaction equations and the specific reference values used in different tables, which may affect the conversion processes discussed.

Who May Find This Useful

This discussion may be useful for students and professionals in chemistry and engineering fields, particularly those interested in combustion processes and thermodynamics.

skaboy607
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Hi,

I am learning about the above at the moment and was wondering when the reaction equations are given or you have worked these out, are they in kg or kmol. I have looked at mixtures and know how to go between the two when given the ultimate or gravimetric analysis but am unsure when I have just the reaction equation.

Also, when dealing with enthalpy of combustion, it is given from steam tables as KJ/Kmol, if wanted to convert this to KJ/Kg, how would I do this. Again from mixtures, I have been trying to do mols multiplied by molecular weight, but this hasn't been giving me the answer I want.

Any help much appreciated.

Thanks
 
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I'm assuming you mean the chemical combustion equation. All chemical equations are given in moles so simply balance them (for stoichiometric). You can then convert each species to its gravimetric weight.

For the enthalys just work in moles its far easier.

I strongly suggest you buy/borrow/steal
Paul Heywood - ICE fundamentals
Richard Stone - Introduction to ICE.

as they contain simply everything you would ever need to know regarding engines.
 
Thanks for your clearing that up for me; I will look into obtaining those books.

With regards to the enthalpies, what if needed to have convert them into kj/kg, how would I go about it?

Thanks
 
For a more general combustion backgound I would recommend "an introduction to combustion" by Stephen Turns (Penn State)

Chriss is right most tables are given on a molar basis. Be careful when using tables from different books because some may have different reference values.
 

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