Compare the conductance of an insoluble salt with soluble one

AI Thread Summary
The discussion centers on the conductance of insoluble versus soluble salts, particularly comparing NaCl and BaSO4. It is established that ionic mobilities increase with temperature due to weakened ionic bonds, which should enhance conductance. There is confusion regarding the correctness of options (c) and (d), as both are cited as correct in various sources, despite the nuances in conductivity behavior of strong versus weak electrolytes. NaCl, being a strong electrolyte, shows negligible variation in conductance with temperature, while BaSO4's dissociation increases with temperature, complicating the comparison. Ultimately, the consensus leans towards option (a) being correct, affirming that temperature positively affects ionic mobility and conductance.
Aurelius120
Messages
269
Reaction score
24
Homework Statement
Conductances of ##\ce{NaCl}## and ##\ce{BaSO_4}## saturated solutions are ##C_{NaCl}## and ##C_{BaSO_4}##. If ##T## is temperature, which of the following is false?
Relevant Equations
NA
1000015589.jpg

Options (a) and (b) are facts and therefore correct.
Since ionic bonds weaken with temperature, ionic mobilities should increase with temperature.
Also in physics, we learnt that the resistance of every material other than conductors (i.e. semi-conductors, insulators and electrolytes decreases with increase in temperature)
The confusion is between options (c) and (d) and both of them are marked as correct answers across different sources on the web.
Since ##\ce{NaCl}## is a strong electrolyte and completely soluble, it's conductances should but vary negligibly with temperature, therefore (c) maybe incorrect. But it does increase.
Option (d) seems true since ##NaCl## is a stronger electrolytes than ##BaSO_4##. But it is also true that
1000015979.jpg

The molar conductivity (and consequently the conductivity & conductance) of a dilute weak electrolyte are much higher than those of strong electrolyte at any concentration. Also ##\ce{BaSO_4}## will show greater increase in dissociation with rise in temperature and thus the statement cannot be true for all temperatures(then again maybe saturated implies no ppt. to dissociate on heating).
So what is the correct answer to this question? Or this question simply wrong?
 
Physics news on Phys.org
I would like to confirm (a). Does ionic mobility increase with T ? Does hot water help or prevent ions to go through ?
 
anuttarasammyak said:
I would like to confirm (a). Does ionic mobility increase with T ? Does hot water help or prevent ions to go through ?
(a) should be correct.
Like I said temperature decreases inter particle forces. Unlike conductors where it increases collisions( to decrease conductance ),it should increase conductance
Otherwise (b) and maybe (c) will be incorrect.
 
Kindly see the attached pdf. My attempt to solve it, is in it. I'm wondering if my solution is right. My idea is this: At any point of time, the ball may be assumed to be at an incline which is at an angle of θ(kindly see both the pics in the pdf file). The value of θ will continuously change and so will the value of friction. I'm not able to figure out, why my solution is wrong, if it is wrong .
Thread 'Trying to understand the logic behind adding vectors with an angle between them'
My initial calculation was to subtract V1 from V2 to show that from the perspective of the second aircraft the first one is -300km/h. So i checked with ChatGPT and it said I cant just subtract them because I have an angle between them. So I dont understand the reasoning of it. Like why should a velocity be dependent on an angle? I was thinking about how it would look like if the planes where parallel to each other, and then how it look like if one is turning away and I dont see it. Since...
Thread 'Correct statement about a reservoir with an outlet pipe'
The answer to this question is statements (ii) and (iv) are correct. (i) This is FALSE because the speed of water in the tap is greater than speed at the water surface (ii) I don't even understand this statement. What does the "seal" part have to do with water flowing out? Won't the water still flow out through the tap until the tank is empty whether the reservoir is sealed or not? (iii) In my opinion, this statement would be correct. Increasing the gravitational potential energy of the...
Back
Top