Components for the angular momentum operator L

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Homework Help Overview

The discussion revolves around the expectation values of the angular momentum operator components, specifically L3 (or Lz), for a wavefunction representing an electron in a hydrogen atom's stationary state characterized by quantum numbers n, l, and m.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants discuss the relationship between the angular momentum operators and the wavefunction, with attempts to express L3 in terms of quantum numbers and the implications of stationary states on these values.

Discussion Status

Some participants have provided insights into the mathematical expressions for L3 and its operator form. There is an ongoing exploration of how stationary states relate to the properties of the angular momentum operator, with hints suggesting the use of spherical harmonics.

Contextual Notes

Participants are navigating the implications of stationary states and the definitions of angular momentum operators, with some assumptions about the mathematical framework being discussed but not fully resolved.

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Homework Statement



Consider wavefunction psi (subscript "nlm") describing the electron in the stationary state for the hydrogen atom with quantum numbers n,l,m and the third component L3 for the orbital angular momentum operator L. What is the expectation value of L3 and of L3^2 for the state described by psi?


Homework Equations





The Attempt at a Solution



L = sqrt(l(l+1)*hbar).

And I think L3 is the same as Lz
Lz = m*hbar
but I don't know what stationary state implies in terms of quantum numbers.
 
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To add to my attempt at a solution:

<L3> = <Lz> = integral(-inf to inf of(psi* x L3operator x psi dz)

L3 operator = (-i x hbar) x (partial / partial x phi)
 
stationary means that it does not depend on time, no time dependence.
 
does that have implications on the orbital angular momentum operator?
 
no, hint: write the solutions in terms of spherical harmonics and use the property of L_z operator on those.
 

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