Concentrations of Pb2+ and Cl2 at equilibrium

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SUMMARY

The discussion focuses on calculating the equilibrium concentrations of Pb2+ and Cl- ions after mixing 50.0 mL of 0.36 M Pb(NO3)2 with 50.0 mL of 1.7 M KCl. The solubility product constant (Ksp) for PbCl2 is given as 1.6 x 10-5. Participants clarify that the Ksp expression should be based on the concentrations of the ions, not the original compounds, and emphasize the importance of identifying the limiting reagent to determine the remaining concentrations at equilibrium.

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Homework Statement


A solution is prepared by mixing 50.0 mL of 0.36 M Pb(NO3)2 with 50.0 mL of 1.7 M KCl. Calculate the concentrations of Pb2+ and Cl2 at equilibrium. Ksp for PbCl2(s) is 1.6 x 10-5.


Homework Equations


I think its Ksp = [Pb(NO3)2][KCl]2

Pb(NO3)2 = 0.018 mol
KCl = 0.085 mol

Is this right? what do i solve for?
 
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Your Ksp is wrong. It should be made of ions concentrations.

Otherwise it is limiting reagent question. Once everything precipitates out, you will be left with the excess of one of the ions involved. Use this concentration to calculate concentration of the other using (correct) Ksp formula.
 

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