Confirming the Nomenclature of C(triplebond)C-CH2-CH3

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SUMMARY

The compound C(triplebond)C-CH2-CH3 is definitively named 1-butyne, as the nomenclature "butyne" alone is ambiguous and can refer to either 1-butyne or 2-butyne. The discussion emphasizes that for alkenes and alkynes, such as hexene and butyne, the position of double and triple bonds should be specified with numbers, particularly when ambiguity exists. The convention of using "1-" is recommended to avoid confusion in chemical naming.

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This is a question which i just want to make sure of..

C(triplebond)C-CH2-CH3

so this would be called butyne
but can it also be called 1-butyne
 
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H-C(triplebond)C-CH2-CH3

is 1-butyne. The name butyne is ambiguous because it could refer to 1-butyne or 2-butyne (see below), which are different molecules.

CH3-C(triplebond)C-CH3
 
alright suppose i was given hexene and i was told to draw it, i would assume the double bond is at 1, right
 
jeahomgrajan said:
alright suppose i was given hexene and i was told to draw it, i would assume the double bond is at 1, right

Yes Right, hexene means 1-hexene and the double bond either on the right or on the left of the structure { C(d.bond)CH2...etc) or (CH3...etc...C(d.bond) }
Only numbers over 1 are given to determine the location of the double and the triple bonds.
 
thanks
 
Silex7 said:
Only numbers over 1 are given to determine the location of the double and the triple bonds.

That's only a convention, and not a widely spread one. Whenever there is a risk of ambiguity, go for 1-somethingene, as it is much cheaper to add 1- each time on paper then to use incorrent reagent once.
 

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