Confusing Stoichiometry Question

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SUMMARY

The discussion centers on a stoichiometry problem involving the reaction of potassium permanganate (KMnO4) and hydrochloric acid (HCl) to produce chlorine gas (Cl2). For part A, the correct mass of KMnO4 required to produce 2.5 L of Cl2 gas at STP is calculated to be 7.05 g. In part B, participants are tasked with determining the volume of 36.0% commercial hydrochloric acid needed, given its density of 1.18 g/mL. The importance of validating numerical answers against expected orders of magnitude is emphasized, particularly through the application of the ideal gas law.

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pure kirk
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I got this question as an example question and I have no clue on how to solve part B

Chlorine can be produced by the reaction:
2KMnO4 + 16HCl ->2KCl + 2MnCl2 + 5Cl2 + 8H2O
(a)What mass of KMnO4 is required to produce 2.5 L of Cl2 gas measured at STP?

For part A I got 7.05 g ( 0.044615 moll)
(b) Calculate the volume of commercial hydrochloric acid required (Commercial grade hydrochloric acid is 36.0% HCl by weight, and has a density of 1.18 g mL^(–1)).
 
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pure kirk said:
I got this question as an example question and I have no clue on how to solve part B

Chlorine can be produced by the reaction:
2KMnO4 + 16HCl ->2KCl + 2MnCl2 + 5Cl2 + 8H2O
(a)What mass of KMnO4 is required to produce 2.5 L of Cl2 gas measured at STP?

For part A I got 7.05 g ( 0.044615 moll)
That is much too low. Please show your calculations.

pure kirk said:
(b) Calculate the volume of commercial hydrochloric acid required (Commercial grade hydrochloric acid is 36.0% HCl by weight, and has a density of 1.18 g mL^(–1)).
Can you start by figuring what mass of HCl you need?
 
DrClaude said:
That is much too low. Please show your calculations.

I got 7.051 g as well:

 
Last edited by a moderator:
I'm sorry for the mistake. I used the density of Cl2 given by WolframAlpha, which is much higher.
 
Looks like they are listing density of a liquid Cl2 - which doesn't make much sense at STP...
 
Borek said:
Looks like they are listing density of a liquid Cl2 - which doesn't make much sense at STP...

Indeed. Very strange.

I feel ashamed because I didn't follow the rule that I always tell my students: when you get a numerical answer, always try to figure out if the order of magnitude makes sense. I should've checked with the ideal gas law...
 
I came.across a headline and read some of the article, so I was curious. Scientists discover that gold is a 'reactive metal' by accidentally creating a new material in the lab https://www.earth.com/news/discovery-that-gold-is-reactive-metal-by-creating-gold-hydride-in-lab-experiment/ From SLAC - A SLAC team unexpectedly formed gold hydride in an experiment that could pave the way for studying materials under extreme conditions like those found inside certain planets and stars undergoing...

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