Contradiction in the laws of thermodynamics?

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SUMMARY

The discussion centers on the apparent contradiction between the second and third laws of thermodynamics regarding entropy. The second law states that entropy in a closed system, such as the universe, always increases, while the third law posits that entropy approaches zero as a system nears absolute zero temperature. Participants explore how the universe's cooling and energy density decrease do not contradict these laws, emphasizing that the forms of energy transition from lower to higher entropy states. The conversation also references Boltzmann's equation, which restricts entropy values and suggests that the universe cannot achieve zero entropy.

PREREQUISITES
  • Understanding of the second law of thermodynamics
  • Familiarity with the third law of thermodynamics
  • Knowledge of Boltzmann's equation (S=k ln W)
  • Basic concepts of cosmic expansion and energy density
NEXT STEPS
  • Research the implications of the second law of thermodynamics in cosmology
  • Study the third law of thermodynamics and its applications beyond perfect crystals
  • Explore Boltzmann's equation and its relevance in statistical mechanics
  • Investigate theories of cosmic expansion, including the big crunch and heat death scenarios
USEFUL FOR

Physicists, cosmologists, and students of thermodynamics seeking to understand the complexities of entropy in the universe and its implications for physical laws.

Maximise24
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The second law of thermodynamics states that the entropy in a system, such as our universe, always increases. The third law, however, says that entropy reaches zero as a system approaches absolute zero temperature.

Our universe has been cooling off since its origin (because of its expansion), accounting for a myriad of interesting physical bodies and processes, but how is this not at odds with both thermodynamical laws? If the system that is our universe is cooling (and indeed slowly approaching absolute zero), its entropy could be said to decrease. The second law however dictates that it must increase invariably. Which is right?
 
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The third law, however, says that entropy reaches zero as a system approaches absolute zero temperature.


Where did you get that?

My version says that at absolute zero the entropy of a perfect crystal is zero.

It says nothing about the approach and perfect crystals are about as common as ideal gasses or hens' teeth.
 
I suppose my confusion comes from the seeming banality of the third law. The first two are very grand in scale and applicable to the entire universe. Why, then, does the third only say something about crystals? What's the relevance?
 
The universe is cooling and its entropy is increasing.
But I think the reason the universe is said to be cooling is because its energy density is decreasing. (Since distant galaxies are getting further away from each other). So its not like cooling a volume of gas inside a box of fixed volume.

The forms of energy in the universe are turning from lower entropy forms into higher entropy forms. (For example, stars are burning up their fuel). So far into the future, it is possible that the structure of our current galaxy e.t.c. will no longer exist, and its contents will be strewn about in a random way. Clearly this is a higher entropy state.
 
The fact/postulate that the entropy is zero at the zero of temperature is also often used, in conjunction with the Second Law, as the basis for saying that it is impossible for any system to reach 0 K. It's beyond my expertise, but I would presume that, in the theory of "infinite" expansion of the universe (note that there are other theories, e.g. the big crunch), the universe would cool to some homogeneous finite (infinitesimal?) temperature.

Furthermore, Boltzmann's equation, S=k ln W, places a strict restriction on the possible values of the entropy. Quantum mechanically, the smallest value W could have is the degeneracy of the ground state. Assuming that the universe does not have a singly-degenerate ground state, then it is impossible for the universe to ever see a zero entropy.
 

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