d-orbital self split or proton split d-orbitals?

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SUMMARY

D-orbitals do not split themselves in the absence of ligands; their splitting is a result of ligand field theory, where the presence of ligands influences the energy levels of the d-orbitals. The concept of d-orbital splitting is fundamentally linked to the interactions between electrons and the electric fields generated by surrounding ligands, rather than the protons from ligands. This discussion emphasizes the importance of understanding ligand interactions in coordination chemistry to explain d-orbital behavior accurately.

PREREQUISITES
  • Understanding of ligand field theory
  • Basic knowledge of coordination chemistry
  • Familiarity with d-orbital electron configurations
  • Concept of electron indistinguishability
NEXT STEPS
  • Research ligand field theory in coordination complexes
  • Explore the role of lone pairs in d-orbital splitting
  • Study the effects of different ligands on d-orbital energy levels
  • Examine case studies of d-orbital splitting in transition metal complexes
USEFUL FOR

Chemistry students, researchers in coordination chemistry, and educators seeking to deepen their understanding of d-orbital interactions and ligand effects.

adf89812
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TL;DR
why don't d-orbitals split themselves, why does it take a ligand? why can't proton split d-orbital?
why don't d-orbitals split themselves because of themselves without the presence of ligands? Electrons are indistinguishable. Why wouldn't it be more correct that protons from a ligand split the d-orbitals rather than the lone-pairs cause d-orbital splitting energy?
 
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adf89812 said:
why don't d-orbitals split themselves because of themselves without the presence of ligands? Electrons are indistinguishable. Why wouldn't it be more correct that protons from a ligand split the d-orbitals rather than the lone-pairs cause d-orbital splitting energy?
Do you have a reference for where you are getting all this from?
 

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