Deriving pV=NkT from N=Na*n and k=R/Na

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Discussion Overview

The discussion revolves around the derivation of the ideal gas law, specifically the relationship pV=NkT, starting from the definitions involving Avogadro's number and the Boltzmann constant. Participants explore the connections between these constants and the ideal gas law, examining assumptions and methods for deriving the equations.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant attempts to manipulate the equations N=Na*n and k=R/Na, reaching N/n=R/k but is unsure how to proceed to derive the ideal gas law.
  • Another participant argues that simply manipulating definitions does not yield the ideal gas law, suggesting that a model of ideal gas behavior is necessary to establish relationships between pressure and other parameters.
  • There is a request for clarification on whether the goal is to convert pV=nRT to pV=NkT, indicating a need for a clear starting point in the derivation process.
  • One participant lists assumptions necessary for the derivation, including the discreteness of gas molecules and their elastic collisions with container walls.
  • A later reply references a video that may provide insight into the derivation process, suggesting that visual aids could be beneficial.

Areas of Agreement / Disagreement

Participants express differing views on the approach to deriving the ideal gas law. Some emphasize the need for a model of ideal gas behavior, while others focus on the manipulation of constants. The discussion remains unresolved regarding the best method to derive the equations.

Contextual Notes

Participants mention assumptions that may limit the applicability of their discussions, such as the non-interaction of gas molecules and the neglect of molecular volume. These assumptions are not universally accepted or detailed, leaving some aspects of the derivation open to interpretation.

Hannah7h
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I've attempted to use N=Na*n -where N is that total number of particles of a gas, Na is the Avogadro constant and n is moles. And then attempted to use k=R/Na -where k is the Boltzmann constant and R is the molar gas constant. I got as far as N/n=R/k but then not sure how to get from this to the final equation- if this is even the right way
 
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You cannot get the ideal gas law by just manipulating the definition of Avogadro number and its relationship with other constants.
Whereas the definition of Avogadro number's is very general, the ideal gas law is valid only for ideal gases. So you need to start with a model of ideal gas and find a relationship between pressure and other parameters.
For example,try to find how the pressure depends on the concentration of particles and their average speed.
You can find the this done in introductory books on kinetic-molecular theory of gases.
 
Hannah7h said:
I've attempted to use N=Na*n -where N is that total number of particles of a gas, Na is the Avogadro constant and n is moles. And then attempted to use k=R/Na -where k is the Boltzmann constant and R is the molar gas constant. I got as far as N/n=R/k but then not sure how to get from this to the final equation- if this is even the right way

Are you trying to convert pV=nRT to pV=NkT?

It would help you are clear on what you want to do, especially on your starting point.

Zz.
 
ZapperZ said:
Are you trying to convert pV=nRT to pV=NkT?

It would help you are clear on what you want to do, especially on your starting point.

Zz.

Ah yeah sorry, it wasn't clear, basically I wanted to know what you would derive pV=nRT from and then how you would derive it from those equations, but also it would be good if you could tell me how to get from pV=nRT to pV=NkT
 
The gas constant is just ##R=k_B N_a##.
 
I think I know what you are looking for.
First, you make a few assumptions :

  • The gas is made up of discrete molecules
  • These molecules don't interact with one another
  • The gas molecules collide elastically with the walls of the container
  • The gas molecules occupy no relevant Volume
  • The gas molecules move equally in all three dimensions
I am just going to stop here because I remembered a video on this:

The derivation starts at 9 minutes
 
Tazerfish said:
I think I know what you are looking for.
First, you make a few assumptions :

  • The gas is made up of discrete molecules
  • These molecules don't interact with one another
  • The gas molecules collide elastically with the walls of the container
  • The gas molecules occupy no relevant Volume
  • The gas molecules move equally in all three dimensions
I am just going to stop here because I remembered a video on this:

The derivation starts at 9 minutes


Ohhh ok, I see how its done now, thank you
 
Glad I could help

Tazerfish :biggrin:
 
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