Determine the amount of americium-241 remaining after 15 years.

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SUMMARY

The discussion centers on calculating the remaining amount of americium-241 after 15 years, given its half-life of 457.699 years. The initial activity of americium-241 in a smoke detector is 33.1 kBq. Participants confirm that after 15 years, approximately 32.4 kBq remains, emphasizing the importance of significant figures in calculations. The consensus is that using more precise values for logarithmic calculations can yield more accurate results, particularly when dealing with exponential decay.

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Homework Statement


The half life of americium-241 is 457.699 years. A typical smoke detector contains 33.1 kBq of americium-241. Determine the amount of americium-242 remaining after 15 years.


Homework Equations


A=Aoe - - 0.693t/T
1/2


The Attempt at a Solution


=33.1xe - (0.693x15/457.699)
A=32.1kBq
 
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About right, although you should use more significant digits than ln(0.5) = 0.693. I got 32.4 for my answer.
 
Rather than use that formula, you could simply use the fact that "The half life of americium-241 is 457.699 years" means that Americium reduces by 1/2 every 457.699 years. 15 years is 15/457.699= 0.033 "half lives" so the sample is reduced by (1/2)^{0.033}= 0.98 times: 0.98(33.1)= 32 mg.

I am using two significant figures for my answer because "15 years", given to 2 significant figures, is the least accurate figure.
 
HallsofIvy said:
I am using two significant figures for my answer because "15 years", given to 2 significant figures, is the least accurate figure.

"15 years" could have meant 15.000 years,; it probably did.

Not extending log(0.5) to more than 3 sig. digits means an error of 0.4/32.357 = 1.24%.
 
HallsofIvy said:
I am using two significant figures for my answer because "15 years", given to 2 significant figures, is the least accurate figure.
You cannot compare the digits like that.
A more extreme example: if the initial radiation is 33.10000 kBq, what is the radiation after 1 second? Sure, the time has just one digit, but the activity will be 33.10000 kBq after 0 seconds and 2 seconds, too. 33kBq would be a wrong answer.
 
mfb said:
You cannot compare the digits like that.
A more extreme example: if the initial radiation is 33.10000 kBq, what is the radiation after 1 second? Sure, the time has just one digit, but the activity will be 33.10000 kBq after 0 seconds and 2 seconds, too. 33kBq would be a wrong answer.

Yes indeed.
Assume it was for 30 years instead of 15. The answer to 2 sig. digits would still have been 32 kBq!

Good point, enforcing precision on the 15 yrs was pointless; but log(0.5) should have been extended to more than 3 sig. digits. Agreed?
 
mfb said:
You cannot compare the digits like that.
Good point - this is exponentiation, not multiplication or division. A 6 month error in the 15 years (though I agree with rude man that the question probably does not intend you to assume that) would be ±3.3%, but the resulting error in 2-n is only 0.08%.
OTOH, if the question had asked how much had decayed, there would be a subtraction involved, and the error would now be back to ±3.3% (not a coincidence).
 
haruspex said:
A 6 month error in the 15 years (though I agree with rude man that the question probably does not intend you to assume that) would be ±3.3% ...

33.1

A 6 month error in the 15 years would have given an error of 0.077%:

let τ = -457.699/ln(0.5) = 660.32

A = 33.1 exp(-t/τ)
A = 33.1 exp(-15/660.32) = 32.357
A' = 33.1 exp(-15.5/660.32) = 32.332
(A - A')/A = 0.077%.
 
rude man said:
A 6 month error in the 15 years would have given an error of 0.077%:
Wasn't 0.08% near enough?
 
  • #10
haruspex said:
Wasn't 0.08% near enough?
You said 3.3%, maybe I misinterpreted?
 
  • #11
rude man said:
You said 3.3%, maybe I misinterpreted?

I wrote that ±6 months on 15 years was a 3.3% error, producing a 0.08% error in the answer.
 
  • #12
rude man said:
Good point, enforcing precision on the 15 yrs was pointless; but log(0.5) should have been extended to more than 3 sig. digits. Agreed?
I would use more digits (or 2^...), but that is a small correction. The difference between your answers is just a calculation error in the first post. I get 32.35671 with the exact value and 32.35655 with the ln(2)-approximation.
The relative error on ln(2) can be compared to the relative error of those 15 years - the answer is not very sensitive to it.
 
  • #13
mfb said:
I would use more digits (or 2^...), but that is a small correction. The difference between your answers is just a calculation error in the first post. I get 32.35671 with the exact value and 32.35655 with the ln(2)-approximation.
The relative error on ln(2) can be compared to the relative error of those 15 years - the answer is not very sensitive to it.

You're right, the OP's first (& only so far) post did not do the arithmetic correctly & I hadn't checked it.
 

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