Does Nitrogen Form NCl3 & NCl5 Like PCl3 & PCl5?

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SUMMARY

Nitrogen does not form NCl3 and NCl5 analogous to phosphorus forming PCl3 and PCl5 due to its inability to utilize free "d" orbitals for hybridization. The discussion highlights that nitrogen lacks the capacity to hybridize to sp3d, which is essential for forming NCl5. In contrast, phosphorus can easily form PCl5 because fluorine atoms are smaller, facilitating the formation of pentahalides.

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would nitrogen form NCl3 and NCl5 as PCl3 and PCl5?
 
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It can't form NCl_{5} because it can't use free "d" orbitals,therefore cannot hybridyze sp^{3}d...

I think it's much easier for phosphorus to form a pentafluoride,becasue the fluor atoms are smaller.

Daniel.
 

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