AcidBathSDMF said:
I'm not sure the ideal gas law takes relativistic effects into account and doesn't apply except in the rest frame. I'm not an expert by any means, but it seems to me that pressure, as a macroscopic model, should be dissected into what's going on in the smaller level. Are we assuming that these gas molecules are billiard balls bouncing around? Assuming this is legitimate, the frame at rest with the box has <v> = 0, where v is velocity of molecules. In a frame that's moving in x-direction, <v_x> will not be zero, and should equal u. v'=x'/t', and v= (v'+u)/(1+uv'/c^2). Supposing for a second that it were possible to take many molecule velocity measurements, one could find <v> of the molecules in the moving frame. This value could be u, and the deviations from it are the random molecular movements that give a pressure. Subtracting this u from the above expression for v to find the molecule speeds in the box, it gives v=v'(1-u^2/c^2)/(1+uv'/c^2). In other words, the measured velocity of the molecular movement is less than that in the rest frame, even after subtracting out the relative velocity of the observer. My intuition tells me that the pressure effects of length contraction of the box are compensated for by the slower moving molecules, and a similar argument for temperature.
Your statement "In other words, the measured velocity of the molecular movement is less than that in the rest frame" is one way of defining temperature which is more formally something like temperature is proportional to the root mean square kinetic energies of the molecules. So that is another way of saying the gas appears to cool down in the moving box. That is a possibility that can not be excluded as the topic of relativistic thermodynamics appears to be hotly debated amongst the experts with peer reviewed published papers contradicting each other.
Does the ideal gas law PV= nRT hold up as a universal law of physics in any inertial reference frame?
The authors of the paper mentioned in the posts above seem to think it is.
The relativistic version of the gas law (according to them) would appear to be:
(P\gamma^2)\left({V \over \gamma}\right) = nR(T\gamma) which reduces to PV = nRT
If we assume that pressure is invariant and also assume the ideal gas law is universal then:
(P)\left({V \over \gamma}\right) = nR({T \over \gamma}) which also reduces to PV = nRT
However at this point we are not absolutely sure the ideal gas law is universal in the relativistic context without modification. The discussion between 1effect and myself that any change of P or T with relative motion would require all melting points and boiling points of all known materials to be adjusted up and down in complicated ways which can not be ruled out, but is certainly far from elegent. However, nature makes the rules and if nature is not elegant we just have to live with that :P
If we assume the ideal gas law is open to modification to make it a universal law, then it could end up as something like this:
P\left({V \over \gamma}\right) = nRT
I suspect the final law will be something altogether different just as the relativistic version of kinetic energy looks nothing like the Newton formula for kinetic energy.
In this very recent paper
http://arxiv.org/PS_cache/gr-qc/pdf/9505/9505045v1.pdf by Matsas he states
“In particular, the question of how temperature transforms under Lorentz transformations led some distinguished physicists to reach exactly the opposite conclusion of other equally distinguished ones.”
In that paper it not clear (to me) if he is talking about a thermometer moving relative to a (stationary?) background radiation or a thermometer co-moving with the background radiation. He does however make the interesting point that there will be differences between thermometers that just measure the infra red part of the spectrum and thermometers that measure the entire spectrum. It also seems that he talking about temperature of a moving object that is measured by a thermometer that is measuring the blackbody radiation of the moving body which is another interpretation of temperature.
Any final definition of temperature would have to be consistent with:
A relativistic ideal gas law.
A relativistic black body radiation law.
A relativistic definition of entropy and enthalpy.
Defining temperature in terms of Entropy can be complicated by issues of combining (or keeping separate?) thermal entropy and “information” entropy. For an example if information entropy and temperature we can look at Hawking’s definition of the temperature of a black hole in terms of its surface area.
For now, it would instructive to investigate further why we have a discrepancy between the pressure computed by the stress-energy tensor and gas pressure evaluated by more simple means. A start would be for someone to give a clear prediction from the stress-energy tensor of how “pressure” varies with velocity.
Does the stress-energy tensor predict P ‘ = P/\gamma or P ‘ = P\gamma or P ‘ = P\gamma^2 or something else?