Bill_K said:
In general, in quantum mechanics, a thing that is time-independent is described by a time-independent wavefunction, and does not in any sense "move". An electron does not orbit the nucleus. A particle in the ground state of a harmonic oscillator does not slosh back and forth. And elementary particles with spin do not rotate.
There is certainly a well-defined sense in which an electron orbits a nucleus -- at least, some electrons.
If you consider electrons in states with L>0, then those states with m
l≠0 have non-zero orbital angular momentum. You can evaluate the "orbital velocity" of the electron wave function by computing the expectation values of the probability density and the
http://en.wikipedia.org/wiki/Probability_current" for the given energy eigenstate |L,m
l>. ISTR that if you then compute the orbital velocity at the expected value of radial position (e.g. the Bohr radius for the ground state of the hydrogen atom), you get a value that accords with the semi-classical model that pictures the electron as a tiny BB of mass m, orbiting in a circular orbit of radius r
Bohr (or appropriate multiple), with angular momentum L. For the |1,1> state I think you find that the orbital velocity is alpha*c, where alpha is the fine-structure constant 1/137.036...
However, the semi-classical model breaks down when you try to apply it to intrinsic spin and a BB-shaped electron with the
http://en.wikipedia.org/wiki/Classical_electron_radius" . When you go down to that tiny scale, where renormalization effects become significant, the computed surface velocity is well in excess of the speed of light...