The discussion centers on proving that the eigenvectors of symmetric matrices are orthogonal when their eigenvalues are distinct. It demonstrates that for eigenvectors v and u corresponding to different eigenvalues λ1 and λ2, the inner product <v, u> must equal zero if λ1 is not equal to λ2. This conclusion arises from the properties of symmetric matrices, which are self-adjoint, leading to the result that (λ1 - λ2)<v, u> = 0. However, if an eigenvalue is repeated, the associated eigenvector space may not be one-dimensional, meaning the eigenvectors are not guaranteed to be orthogonal. Thus, the orthogonality of eigenvectors is contingent on having distinct eigenvalues.