Ejection of Only one electron by a Photon in the Photoelectric effect

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SUMMARY

The discussion clarifies that in the photoelectric effect, one photon ejects only one electron due to the nature of the photoemission process, where the entire energy of the photon is absorbed in a single event. While high-energy photons can eject multiple electrons, this occurs through different processes such as the Auger effect, not the photoelectric effect. The Auger process involves the ionization of an atom and subsequent electron transitions, resulting in the emission of additional electrons. Understanding the distinct energy spectra of these processes is crucial for identifying the mechanisms at play.

PREREQUISITES
  • Understanding of the photoelectric effect and photoemission
  • Knowledge of the Auger effect and its mechanisms
  • Familiarity with Compton scattering and its implications
  • Basic principles of electron energy spectra analysis
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  • Study the differences between photoelectric effect and Compton scattering
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Zahid Iftikhar
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Hi
I am surprised to know why only one photon in photoelectric effect ejects one electron only. What if a high energy photon (not necessarily x-ray or gamma ray, which may cause Compton effect or pair production)hits the metal, say it has energy double or triple of that of the work function? Why does not it eject two or more electrons?
Please help.
Regards
 
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That process is possible but very unlikely. In general reactions get less likely the more particles have to be involved.
 
Please some more information.
Regards
 
Zahid Iftikhar said:
Hi
I am surprised to know why only one photon in photoelectric effect ejects one electron only. What if a high energy photon (not necessarily x-ray or gamma ray, which may cause Compton effect or pair production)hits the metal, say it has energy double or triple of that of the work function? Why does not it eject two or more electrons?
Please help.
Regards

First of all, an energetic photon may cause more than one electron to be ejected, but NOT via the photoelectric effect. The Auger process can certainly result in more than one electron being ejected per photon.

But for the photoelectric (or more accurately, a photoemission) process, the entire energy of the photon is absorbed on one shot. There is no partial absorption. This is, by definition, the photoemission process. If the process involves anything else, then it is called something else.

Zz.
 
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ZapperZ said:
First of all, an energetic photon may cause more than one electron to be ejected, but NOT via the photoelectric effect. The Auger process can certainly result in more than one electron being ejected per photon.

But for the photoelectric (or more accurately, a photoemission) process, the entire energy of the photon is absorbed on one shot. There is no partial absorption. This is, by definition, the photoemission process. If the process involves anything else, then it is called something else.

Zz.
Thanks indeed for your kind reply. To my understanding Auger process involves ionization of an atom due to emission of inner electron after being hit by high energy photon. The vacancy thus created is filled by some electron from higher orbits. Another photon thus created hits another electron and kicks it out. In all this chain, still one photon knocks out one electron. This is what I want to know. Even in Compton effect, we see same thing happens. Please spare some more time for my query.
High regards.
 
Zahid Iftikhar said:
Thanks indeed for your kind reply. To my understanding Auger process involves ionization of an atom due to emission of inner electron after being hit by high energy photon. The vacancy thus created is filled by some electron from higher orbits. Another photon thus created hits another electron and kicks it out. In all this chain, still one photon knocks out one electron. This is what I want to know. Even in Compton effect, we see same thing happens. Please spare some more time for my query.
High regards.

But that original one photon that entered the material has now kicked out more than one electron. So that in itself has already answered your original question. But now comes the details, because, for example, how would we know that an Auger process took place?

This is where one has to look at the details of the emitted electron spectrum. The Auger process has a distinct spectrum where by it actually gives you info about the core level states. A "compton scattering" does not, because the compton spectrum is typically broad!

Besides, there's another important issue here. When an energetic electron bumps into another electron, this is a "lossy" process in terms of energy of the original electron. In fact, an electron that already has enough energy to escape a material will tend to lose that energy quite easily if it bumps into another electron before it escapes the material. This is why metals are usually poorer photocathodes than semiconductors, because metals have more free electrons than semiconductors. So a "compton process" inside a solid is often detrimental to the emission of electrons from that solid.

Zz.
 
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