Electrolyte that doesn't react with ZnO for electrolysis of water

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    Electrolysis Water
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Discussion Overview

The discussion centers on identifying an appropriate electrolyte that does not react with zinc oxide (ZnO) for the purpose of electrolysis of water. Participants explore various options and considerations regarding the chemical properties of potential electrolytes.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant inquires about electrolytes that do not react with ZnO, noting that common electrolytes like NaOH and KOH are unsuitable due to their reactivity.
  • Another participant suggests sodium sulfate as a possible electrolyte.
  • A follow-up response expresses interest in sodium sulfate but seeks additional alternatives.
  • It is proposed that a neutral electrolyte is necessary because ZnO is amphoteric, and that stable anions that do not oxidize should be considered. The participant mentions that salts of strong acids and bases might be neutral, but cautions against using chlorides.
  • Potential candidates mentioned include sulfates of sodium, lithium, and potassium, as well as perchlorates, though the latter may be more costly.

Areas of Agreement / Disagreement

Participants do not reach a consensus on a single electrolyte, and multiple competing views regarding suitable options remain present throughout the discussion.

Contextual Notes

Participants express uncertainty about the stability and reactivity of various anions in the context of electrolysis, and there are unresolved considerations regarding the cost and availability of suggested electrolytes.

kevin_tee
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Does anybody know electrolyte that doesn't react with ZnO for electrolysis of water? NaOH and KOH is good electrolyte for electrolysis of water, but it react with ZnO. Thanks.:smile:
 
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Sodium sulfate?
 
Thanks, I will try using sodium sulfate but are there any more possible electrolytes?
 
You need something that is neutral, as ZnO is amphoteric. Most salts of strong acids and strong bases will be neutral in solutions (or close to neutral) - but you need a stable anion, that would not get oxidized, which means of the obvious ones chlorides are out of the question. Sulfates of sodium, lithium, potassium sound best to me, perhaps perchlorates would be good as well - but definitely more expensive..
 

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