- #1
Nabla94
- 3
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Hello together,
I'm interested in the electron-hole exchange energy. I would like to see how and have a proof why electron-hole exchange works. Is it symmetric or antisymmetric? More specific, I would like to have a proof that exchange with paired electrons in a molecule can be neglected. However - the more general the better.
In order to proof it, one probably has to regard the many-electron exchange interaction. I found
The Universal Hamiltonian of the Exchange Interaction for the System of Particles with an Arbitrary Spin j - E. Orlenko (2007)
but I don't quite get the notation and they do not mention electron-hole exchange.
I'm grateful for any hint, help or tip for literature.
I'm interested in the electron-hole exchange energy. I would like to see how and have a proof why electron-hole exchange works. Is it symmetric or antisymmetric? More specific, I would like to have a proof that exchange with paired electrons in a molecule can be neglected. However - the more general the better.
In order to proof it, one probably has to regard the many-electron exchange interaction. I found
The Universal Hamiltonian of the Exchange Interaction for the System of Particles with an Arbitrary Spin j - E. Orlenko (2007)
but I don't quite get the notation and they do not mention electron-hole exchange.
I'm grateful for any hint, help or tip for literature.