Energies of interaction between molecules

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SUMMARY

The discussion focuses on estimating the energies of interaction between hydrogen and nitrogen molecules at 25 °C, using the London dispersion force equation, V = -3/4 α²I/r⁶. The participants confirm that the approach is correct for hydrogen, with a specific calculation involving the polarizability value. It is established that polarizability values can be sourced from the reference "Hirschfelder, Curtiss, and Bird." This discussion emphasizes the importance of accurate molecular property values in calculations of intermolecular forces.

PREREQUISITES
  • Understanding of London dispersion forces
  • Familiarity with molecular polarizability
  • Knowledge of intermolecular interaction equations
  • Basic thermodynamics principles at 25 °C
NEXT STEPS
  • Research polarizability values in "Hirschfelder, Curtiss, and Bird"
  • Learn about the application of the London dispersion force equation
  • Explore intermolecular forces in different gases
  • Study the impact of temperature on molecular interactions
USEFUL FOR

Chemistry students, researchers in molecular physics, and anyone interested in calculating intermolecular forces and their applications in thermodynamics.

burns96
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Homework Statement


Estimate the energies of interaction at 25 °C between (i) two hydrogen molecules and (ii) two nitrogen molecules, if each pair is separated by 0.3 nm. Explain fully and clearly your reasoning and any assumptions you make in your answer. State the source of the values of any molecular properties you use in your calculation.

Homework Equations


Would I use the London dispersion force equation for this?
V = -3/4 α2I/r6

The Attempt at a Solution


so for hydrogen -3/4 x α2 x 1312 x 103/(3 x 10-10)6
Is this the right approach? Not sure where to get a value for polarisability from
 
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burns96 said:

Homework Statement


Estimate the energies of interaction at 25 °C between (i) two hydrogen molecules and (ii) two nitrogen molecules, if each pair is separated by 0.3 nm. Explain fully and clearly your reasoning and any assumptions you make in your answer. State the source of the values of any molecular properties you use in your calculation.

Homework Equations


Would I use the London dispersion force equation for this?
V = -3/4 α2I/r6

The Attempt at a Solution


so for hydrogen -3/4 x α2 x 1312 x 103/(3 x 10-10)6
Is this the right approach? Not sure where to get a value for polarisability from

This looks right to me.
Polarizabilities should be given in Hirschfelder, Curtiss, and Bird.
 

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