Energy Conservation in an expanded 1D box

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SUMMARY

The discussion centers on the conservation of energy in quantum mechanics when a one-dimensional particle in a box expands from length L to 2L. It concludes that during the expansion, the Hamiltonian changes due to the alteration of the potential V(x), which becomes time-dependent. Consequently, the energy expectation value is not conserved because an external force does work on the system. The wavefunction remains unchanged but can be expressed as a superposition of the new wavefunctions corresponding to the updated infinite square well (ISW) potential.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly wavefunctions and Hamiltonians.
  • Familiarity with the concept of infinite square well (ISW) potentials.
  • Knowledge of time-dependent Schrödinger equation and its implications.
  • Basic grasp of conservation laws in physics, specifically energy and momentum.
NEXT STEPS
  • Study the implications of time-dependent potentials in quantum mechanics.
  • Learn about the time-dependent Schrödinger equation and its applications.
  • Explore the concept of superposition in quantum systems.
  • Investigate the effects of external forces on quantum systems and energy conservation.
USEFUL FOR

Students and enthusiasts of quantum mechanics, particularly those interested in the implications of potential changes on energy conservation in quantum systems.

dLo R6
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I am fairly new to QM and am learning many of the basics right now. We were just discussing conservation of operators (energy, momentum, etc) and I recalled a problem proposed in my textbook about a 1D particle in a box of length L. at a time t, the box suddenly expands to t=2L, in which time the wavefunction does not have time respond. it asked if energy (more specifically, <H>) was conserved during the time that the wall moves.

i'm assuming that the laws of conservation aren't broken and that the Hamiltonian does not change. but then does the fact that the box expanded at a specific time, mean that then the potential V(x) is now a function of time? so then is energy is not conserved since I have to consider the potential in the Hamiltonian now?
 
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OK now I'm assuming that since the box changes, the potential does change and thus <H> is not equal to <H'>. Is this correct?
 
That's correct. An external force moved the wall, doing work on the system, so the energy of the system is not conserved.
 
Yes, technically your potential is now a function of time, but you don't want to solve the time-dependent Schrödinger equation. Because the wavefunction doesn't change, Your old wavefunction is a superposition of your new set of wavefuncitons describing your new ISW potential.
 

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