Energy eigenvalue for particle in a box

In summary, the problem is to find the probability and mean energy of a measurement of the energy eigenvalue for a given wavefunction inside an infinite square well. This can be done by finding the coefficients of the wavefunction as a linear combination of the energy eigenfunctions, using the orthogonality and normalization properties of the eigenfunctions.
  • #1
rias
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Hello all, I'm stuck on this question, and I would appericate if someone can tell me how to start cracking the problem.

I have a infinite square well, and is given a wavefunction that exist inside the well. The problem is to find the probability that a measurement of the energy will result in a certain given energy eigenvalue. Also I have to find teh mean energy.


Thanks in advance.
 
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  • #2
The wavefunction that you're given is not one of the eigenfunctions of the inifinite square well, right?

In general, any wave function that satisfies the boundary conditions for a physical situation (such as the infinite square well) can be written as a linear combination of the energy eigenfunctions:

[tex]\psi = a_1 \psi_1 + a_2 \psi_2 + a_3 \psi_3 + ...[/tex]

where [itex]\psi_1[/itex] has energy eigenvalue [itex]E_1[/itex], and [itex]a^*_1 a_1[/itex] gives the probability that the particle has energy [itex]E_1[/itex]. So your problem is to find out what the [itex]a_k[/itex] are, or at least some of them.

The energy eigenfunctions are orthogonal, which means that

[tex]\int {\psi^*_j \psi_k dx} = 0[/tex]

whenever [itex]j \ne k[/itex]. Suppose that the eigenfunctions are also normalized so that

[tex]\int {\psi^*_k \psi_k dx} = 1[/tex]

for any k. Take the first equation above and multiply through by (say) [itex]\psi^*_2[/itex]:

[tex]\psi^*_2 \psi = a_1 \psi^*_2 \psi_1 + a_2 \psi^*_2 \psi_2 + a_3 \psi^*_2 \psi_3 + ...[/tex]

Then integrate both sides. Look at what happens to the integrals on the right side, and you should see how to calculate [itex]a_2[/itex], and how to generalize this method to any value of k.
 

1. What is the concept of energy eigenvalue for a particle in a box?

The concept of energy eigenvalue for a particle in a box is a fundamental concept in quantum mechanics that describes the quantized energy levels of a particle confined in a box. This means that the energy of the particle can only take on certain discrete values, and cannot have any value in between these levels.

2. How is the energy eigenvalue measured for a particle in a box?

The energy eigenvalue for a particle in a box is typically measured through mathematical calculations using the Schrödinger equation. This equation takes into account the size and shape of the box, as well as the properties of the particle, to determine the allowed energy levels.

3. What is the significance of the energy eigenvalue in quantum mechanics?

The energy eigenvalue is significant in quantum mechanics because it represents the quantized nature of energy in the microscopic world. It also helps to explain the behavior of particles in confined spaces and can be used to predict the behavior of quantum systems.

4. How does the energy eigenvalue change as the size of the box is altered?

The energy eigenvalue for a particle in a box will change as the size of the box is altered. As the size of the box decreases, the energy levels become more closely spaced, and the energy eigenvalues increase. Conversely, as the size of the box increases, the energy levels become more widely spaced, and the energy eigenvalues decrease.

5. Is the energy eigenvalue the same for all particles in a box?

The energy eigenvalue for a particle in a box will vary depending on the properties of the particle, such as its mass and charge. This means that different particles in the same box may have different energy eigenvalues, but they will still follow the same quantized energy levels as described by the Schrödinger equation.

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