Energy of an electron in a uranium atom

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SUMMARY

The discussion focuses on calculating the energy of an electron in a uranium atom (Z=92) using special relativity and reduced mass concepts. The formula for the energy is given as En = u*(9e9)^2*e^4*Z^2/(2(h bar)^2*n^2). The reduced mass is calculated using u = Me * M(nucleus)/(Me + Mnucleus), where the mass of the uranium nucleus is approximately 238 times the mass of a proton. The participants conclude that the relativistic correction is more significant than the reduced mass correction for uranium, with a noted correction of 35% for the energy.

PREREQUISITES
  • Understanding of special relativity, specifically the formula m = m0/(1-v^2/c^2)
  • Knowledge of reduced mass calculations in atomic physics
  • Familiarity with quantum mechanics concepts, particularly energy levels in atoms
  • Basic understanding of electrostatic forces and centripetal acceleration in atomic models
NEXT STEPS
  • Study the derivation and implications of the reduced mass in multi-particle systems
  • Learn about relativistic corrections in quantum mechanics, particularly for heavy elements like uranium
  • Explore the calculation of electron velocities in atomic orbits using Coulomb's law
  • Investigate the differences in energy levels between hydrogen and heavier atoms, focusing on Z=92
USEFUL FOR

Physics students, researchers in atomic and nuclear physics, and anyone interested in the relativistic effects on electron behavior in heavy atoms like uranium.

StephenD420
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using special relativity m = m0/(1-v^2/c^2) on an electron orbiting with a speed of 2.01 * 10^8 m/s in an atom,estimate the percentage corrections to the n=1 energy in a uranium (Z=92) atom.

so to find the energy I first need the reduced mass, u, for En = u*(9e9)^2*e^4*Z^2/2(h bar)^2*n^2.
How do I find the reduced mass? I know it is u = Me * M(nucleus)/(Me + Mnucleus)
but how can I find the mass of the nucleus. The answer my professor gave was there was a correction of 35%, but I cannot compare the energies until I have the reduced mass that will be in the first energy, then I change the reduced mass using the special relativity formula above, and then find the n= 1 energy again and find the percent difference.

I would really appreciate any help.
Thanks.
Stephen
 
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Would the reduced mass be = (Me * (92*Mproton))/(Me +92*Mproton)?

Please, a quick reply would be greatly appreciated.

Thanks.
Stephen
 
Just a quick aside as a part of the same problem for a hydrogen at n=1 state with a reduced mass of 9.10444*10^(-31) kg with special relativistic effects makes u = 9.10468*10^(-31) kg
to make E =u*(8.988*10^9)^2*(1.6022*10^(-19))^4/ (2(1.0546*10^(-34))^2)

which makes the percent correction for hydrogen .0027%.

is this right?
 
StephenD420 said:
Would the reduced mass be = (Me * (92*Mproton))/(Me +92*Mproton)?

Please, a quick reply would be greatly appreciated.

Thanks.
Stephen

Actually you would use mass of the uranium nucleus in that formula. That would be about 238*Mproton because there are a lot of neutrons in there too. But you needn't bother. The reduced mass correction is insignificant compared with the relativistic correction in uranium. Just compute that one.
 
How would I find the relativistic mass without knowing the reduced mass?? What formula should I use to find the reduced mass?

Thanks
Stephen
 
StephenD420 said:
How would I find the relativistic mass without knowing the reduced mass?? What formula should I use to find the reduced mass?

Thanks
Stephen

You have the right formula for the reduced mass. You should use the mass of the U nucleus instead of Mproton. But you are going to find the reduced mass is really really really close to being the same as Me because the nucleus is so heavy. The important mass correction is the one you had in your problem statement m = m0/sqrt(1-v^2/c^2). I just noticed you left the square root out of that formula. Just find that correction.
 
so use m0=Me is this what you are saying??
 
StephenD420 said:
so use m0=Me is this what you are saying??

That's exactly what I'm saying.
 
ok...so I emailed my professor and he said to use the same numbers as in the following problem:

The problem was to find the speed of an electron in a uranium atom in n=1.
so I started with r = (hbar)^2/ u*(9e9)(92)e^2=5.7549*10^-13 m with u = 9.10444*10^(-34) kg which is the reduced mass of a hydrogen atom then I went to F=ke^2/r^2 = mv^2/r and found v^2 = 2.10 * 10^7 m/s but my professor says that it is 2.01*10^8 m/s.

So I do not have the numbers right in this problem and so my numbers for the problem of the thread is wrong. Where am I messing up??

Please, Please help. My professor just said that I should think about it and the fact that hydrogen is Z=1 and uranium is Z=92.

Thanks.
Stephen
 
  • #10
StephenD420 said:
ok...so I emailed my professor and he said to use the same numbers as in the following problem:

The problem was to find the speed of an electron in a uranium atom in n=1.
so I started with r = (hbar)^2/ u*(9e9)(92)e^2=5.7549*10^-13 m with u = 9.10444*10^(-34) kg which is the reduced mass of a hydrogen atom then I went to F=ke^2/r^2 = mv^2/r and found v^2 = 2.10 * 10^7 m/s but my professor says that it is 2.01*10^8 m/s.

So I do not have the numbers right in this problem and so my numbers for the problem of the thread is wrong. Where am I messing up??

Please, Please help. My professor just said that I should think about it and the fact that hydrogen is Z=1 and uranium is Z=92.

Thanks.
Stephen

I'm not following all of that, but when you do F=ke^2/r^2 = mv^2/r it looks like you are balancing electric force and centripetal acceleration. But why ke^2/r^2? Isn't the the charge of the nucleus 92e, not e?
 
  • #11
ahhh...you are right. so would the force =k92e^2/r^2=mv^2/r?? So I do not need to worry about the reduced mass, just use the mass of electron,9.1094*10^(-31) kg, or the reduced mass of an electron proton pair, 9.10444*10^(-31) kg??

Thanks.
Stephen
 
  • #12
StephenD420 said:
ahhh...you are right. so would the force =k92e^2/r^2=mv^2/r?? So I do not need to worry about the reduced mass, just use the mass of electron,9.1094*10^(-31) kg, or the reduced mass of an electron proton pair, 9.10444*10^(-31) kg??

Thanks.
Stephen

Yes, use Me. Since you don't seem to believe me find the reduced mass in uranium. Tell me how close it is to Me. There is absolutely no reason to use the reduced mass of an electron proton pair. That has nothing to do with this problem at all.
 

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