Energy required to fully ionize Uranium

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Homework Help Overview

The discussion revolves around determining the maximum wavelength of light required to fully ionize Uranium, specifically to the U92+ state, by stripping it of all electrons. The participants are considering direct ionization while neglecting non-linear effects.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants explore the energy required to remove electrons from different energy levels, questioning whether to calculate the energy for each electron or focus on the hardest electron to remove. There is discussion about the significance of the outermost electrons in the ionization process.

Discussion Status

Some participants have offered clarifications regarding the problem's requirements, emphasizing the need to identify the highest energy photon necessary for ionization rather than the total energy for all electrons. There is an emerging understanding of focusing on the electron closest to the nucleus.

Contextual Notes

Participants are navigating the complexities of ionization energy and the specific requirements of the problem, including the distinction between total energy and the energy of the hardest-to-remove electron.

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1. What is the maximum wavelength of light required to fully ionised Uranium to U92+, i.e.
strip it of all electrons and leaving a bare nucleus? For simplicity, only consider direct
ionisation and neglect non-linear effects.





Attempt at solution

Ok, so the electron structure of the atom is 2,8,18,32,21,9,2. Ionization will be the energy required to remove an electron that is the least tightly bound to the atom. In order to completely ionize the atom do I calculate the energy required to ionize each electron at their respective energy levels? I am a bit confused as to how to tackle the problem.
Thanks
 
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doppeled said:
What is the maximum wavelength of light required to fully ionised Uranium to U92+, i.e.
strip it of all electrons and leaving a bare nucleus? For simplicity, only consider direct
ionisation and neglect non-linear effects.

[...]

In order to completely ionize the atom do I calculate the energy required to ionize each electron at their respective energy levels?
I think this is where your confusion is coming from: these two statements of the problem are different.

You are not asked the total energy to ionize the atom, but the highest energy photon needed. Consider that one photon removes one electron, what electron will be the hardest to remove?
 
Ah yes, I think I understand now. So just a matter of calculating the energy required to remove an electron closest to the nucleus, which is in the ground state.

Thank you for your help.
 
doppeled said:
Ah yes, I think I understand now. So just a matter of calculating the energy required to remove an electron closest to the nucleus, which is in the ground state.
Just to make clear, it will be the energy needed to remove the last electron.
 
Yes so during ionization the outermost, least bound electrons will be removed first, and so by calculating wavelength required to remove the last electron we have a sufficient energy to completely ionize.
 

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