Equilibrium Constant for Water Dissociation

[vinayakp]

How to derive equillibrium constant (K) of reaction with respect to water eq. constant (KH2O) ?

Reactions

H+ + HCO3- ----------> H2CO3


H+ + CO3-2 -----------> HCO3-

Fe2+ + Cl- ----------> FeCl+

Fe2+ + CH3COO- ----------> Fe( CH3COO)+

 

[Astronuc]

Please attempt to write the equations oneself. Is there not an example in one's Chemistry textbook?

 

[symbolipoint]

Here is just a wild guess about the dissociation constant for water; I do not know if it is actually how the constant was found:

Conductivity Measurements!

Pure, extra pure water could have been used, assuming dissociation would occur something like, in the simplest manner H2O <===> H+ + OH-
The resulting ions in solution will conduct electricity, therefore measurement of conductivity may correlate with concentration of the ions.

The concentration of the H2O is assumed not to change and does not occur in the mathematical expression. K = [H]*[OH]

Were you really asking about the thermodynamics of the process?