Equilibrium Constnant Discrepancy: SO2 + O2 -> Kc = 279

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Discussion Overview

The discussion revolves around a discrepancy in the equilibrium constant (Kc) for the reaction of sulfur dioxide (SO2) and oxygen (O2) to form sulfur trioxide (SO3). Participants are attempting to reconcile their calculated value of Kc with a value provided in a textbook, while addressing the necessary information for accurate calculations.

Discussion Character

  • Homework-related
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant calculates Kc as 3.61 based on given amounts of SO2 and O2 but notes that the textbook states it should be 279.
  • Another participant questions whether all necessary information has been provided to accurately calculate the equilibrium constant, suggesting that more data is likely needed.
  • A later reply clarifies the reaction formula as 2SO2 + O2 = 2SO3 and mentions that 0.85 moles of SO3 were present at equilibrium.
  • Participants emphasize that the initial amounts of reactants do not represent the equilibrium concentrations, indicating a need for further calculations based on stoichiometry.
  • There is a suggestion to calculate the remaining amounts of SO2 and O2 after the reaction to determine the correct equilibrium concentrations or partial pressures.

Areas of Agreement / Disagreement

Participants do not reach a consensus, as there are multiple competing views regarding the sufficiency of the provided information and the calculations needed to resolve the discrepancy in Kc values.

Contextual Notes

Limitations include missing details about the final concentrations of all gases at equilibrium and the initial conditions that may affect the calculations. The discussion highlights the importance of stoichiometric relationships in determining equilibrium states.

nhrock3
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we put 64 grams of SO2 and 32 grams of oxygen
it reaches equilibrium in 1000k
what is the equlibrium constnant
[tex]\frac{(\frac{0.85}{5})^2}{(\frac{1}{5})^2\frac{1}{5}}=3.61[/tex]

but the book says 279
why
?
 
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Is this whole question? I am sure it is not, I am sure there were more information provided that could be used to calculate final amounts of all three gases.

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you are correct i forgot to mention the formula
2SO2+O2=2SO3
and we put 0.85 moles of SO3
 
This is probably still not all or you are not quoting the information properly. So far you have listed substances that were put into the mixture, I believe these amounts are not what was present at equilibrium.

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methods
 
i forgot to mention that this whole thing in 5 litter container
 
And this is probably still not all. If the mixture was left to react till it reached equilibrium, final concentrations are not the initial ones. So far you have listed what was put into the container - that's not enough to calculate final concentrations.

Any other information you have forgot to mention?

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sorrry again
in the end we find 0.85 moles of SO3
 
You won't get much more from me: use stoichiometry to calculate how much sulfur dioxide and oxygen were left, then use these values to calculate concentrations (or partial pressures) of all gases.

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