Equilibrium: Le Chatelier's Principle and CaCO3 Decomposition

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SUMMARY

The discussion focuses on Le Chatelier's Principle as it applies to the decomposition of calcium carbonate (CaCO3) into calcium oxide (CaO) and carbon dioxide (CO2). When the volume of the container is halved, the equilibrium shifts to the left to counteract the change, reducing the pressure by favoring the formation of reactants. The key takeaway is that the presence of gaseous CO2 influences the equilibrium position, necessitating a reaction to restore the equilibrium partial pressure.

PREREQUISITES
  • Understanding of Le Chatelier's Principle
  • Knowledge of chemical equilibrium concepts
  • Familiarity with state changes in chemical reactions
  • Basic principles of gas behavior and pressure
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  • Study the effects of volume changes on gas-phase equilibria
  • Learn about the equilibrium constant and its dependence on temperature and pressure
  • Explore the implications of state changes in chemical reactions
  • Investigate the role of partial pressures in determining equilibrium positions
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Chemistry students, educators, and anyone studying chemical equilibrium and reaction dynamics will benefit from this discussion.

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Homework Statement



I had a question on a test and I got the wrong answer, but I still don't understand why. It was a Le Chatelier problem about the equilibrium shift, and it described the decomposition of CaCO3

CaCO3(s) <->CaO(s) + CO2(g)

The question asked something along the lines of "If the volume of the container was halved, in what direction would equilibrium shift?"

Homework Equations



N/A

The Attempt at a Solution



I thought it wouldn't shift at all because the CO2 is in a different state than the CaCO3 and CaO, and because one of the ways you can change an equilibrium system without disturbing the equilibrium was to have reactants in different states, but apparently I was wrong. Can you please explain to me why the equilibrium would shift left even if there are no gas entities? Is it just to reduce pressure because there is 1 reactant entity for every 2 product entities? Thanks.
 
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The equilibrium is determined solely by the equilibrium value of the CO2 gas partial pressure. If the container volume is halved, half of the CO2 will have to react with CaO to re-establish the equilibrium partial pressure.
 

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