Experimental evidence for the ground state of energy

In summary, the Schrödinger equation for a harmonic oscillator predicts the ground state energy of a particle to be ω/2. Experimental evidence, such as the Casimir effect, supports this prediction by showing that in order to change the ground state energy, work must be done on the oscillator. This is due to the fact that each mode of the electromagnetic field between two plates behaves like a harmonic oscillator in its ground state, and changing the separation of the plates changes the frequencies of these oscillators and thus their ground state energy. While there is no direct experiment that proves the impossibility of a zero ground state energy, the consistency of these results with the quantum theory of the harmonic oscillator strongly suggests that it is not achievable.
  • #1
PerpStudent
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I hope this is a coherent question: Solving the Schrödinger equation for energy eigenvalues for a harmonic oscillator leads to the ground state of the energy for a particle being ω/2. What is the experimental evidence that this is, in fact, the lowest achievable energy and that zero energy is not achievable?
 
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  • #2
Suppose you have a harmonic oscillator in the ground state, and you slowly increase the value of ω. You will have to do work on the oscillator to accomplish this. The ground state energy changes by (change in ω)/2, so this is the amount of work you have to do on the oscillator.

This is seen in, for example, the Casimir effect: http://en.wikipedia.org/wiki/Casimir_effect

In the Casimir effect, there's basically a harmonic oscillator corresponding to each mode of the electromagnetic field that can exist between the two plates. In general, these oscillators sit in their ground state. Changing the separation of the plates changes the frequencies of these oscillators, changing their ground state energy. So you have to do work in order to move the plates. In other words, there is a force between the plates that you can calculate from W = Fd. This is one way of understanding how the Casimir force arises.
 
  • #3
Thanks for your response. I see that the observed forces in the Casimir effect are consistent with the quantum theory of the harmonic oscillator. However, is there any experiment that demonstrates that the ground state of the energy for a particle cannot be zero? I understand that a zero ground state energy would be inconsistent with the theory, but I am searching for some experiment that clearly shows that it is impossible to have a zero ground state. Perhaps some experiment performed near absolute zero temperature?
 

1. What is the ground state of energy?

The ground state of energy is the lowest possible energy state that an atom or molecule can have. It is also known as the "zero-point energy" or "lowest energy level".

2. How is the ground state of energy determined experimentally?

The ground state of energy can be determined experimentally through various methods such as spectroscopy, electron energy loss spectroscopy, and x-ray photoelectron spectroscopy.

3. What is the significance of the ground state of energy in chemistry?

The ground state of energy is significant in chemistry because it is the starting point for understanding the behavior and properties of atoms and molecules. It is also used as a reference point for measuring the energy changes during chemical reactions.

4. Can the ground state of energy change?

Yes, the ground state of energy can change if the atom or molecule absorbs or releases energy through processes such as excitation or de-excitation. However, the ground state is the most stable and lowest energy state, so it is the state that atoms and molecules tend to return to after undergoing energy changes.

5. How does the ground state of energy relate to the electron configuration of an atom?

The electron configuration of an atom is determined by the arrangement of electrons in different energy levels. The ground state of energy is the lowest energy level and corresponds to the electron configuration with the most stable arrangement of electrons. It is also the state that atoms tend to return to after undergoing energy changes, making it an important factor in predicting and understanding chemical behavior.

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