Feynman, Hibbs Transition Amplitudes and Energy

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SUMMARY

The discussion centers on the transition amplitudes in quantum mechanics as presented in Feynman & Hibbs' "Quantum Mechanics and Path Integrals." The key formula derived for the probability of transition from state n to state m is given by $$P(n\rightarrow m) = \frac{2\pi}{\hbar}|V_{mn}|^2\rho(E_n)T$$, where |V_{mn| is the matrix element of the perturbation potential and ρ(E) is the density of states. The confusion arises regarding the assertion that the energy in the final state equals the initial state energy, particularly in the context of continuous energy spectra. The discussion highlights the importance of the delta function in the derivation of transition probabilities, especially as time approaches infinity.

PREREQUISITES
  • Understanding of quantum mechanics principles, specifically perturbation theory.
  • Familiarity with the concepts of transition amplitudes and probabilities.
  • Knowledge of the mathematical formulation of integrals involving delta functions.
  • Experience with Feynman path integrals and their applications in quantum mechanics.
NEXT STEPS
  • Study the derivation of transition probabilities in quantum mechanics, focusing on time-dependent perturbation theory.
  • Explore the implications of the delta function in quantum transitions and its role in continuous energy spectra.
  • Review the mathematical techniques for evaluating integrals involving oscillatory functions, particularly in the context of quantum mechanics.
  • Investigate the photoelectric effect and its relation to transition amplitudes as discussed in Feynman & Hibbs.
USEFUL FOR

Students and researchers in quantum mechanics, particularly those studying perturbation theory, transition amplitudes, and the implications of continuous energy spectra. This discussion is also beneficial for anyone seeking to deepen their understanding of Feynman path integrals and their applications in quantum physics.

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I’m currently self-studying from Feynman & Hibbs Quantum Mechanics and Path Integrals, but having trouble with a statement in the chapter on time-dependent perturbations.

Background: They define
$$V_{mn}(t_c) = \int_{-\infty}^\infty \phi_m^*(x_c)V(x_c,t_c)\phi_n(x_c)\,dx_c,$$
where V(x,t) is the perturbation potential, and \phi_{m/n}(x_c) are unperturbed eigenfunctions of energy E_{m/n}. By looking at the first-order expansion for V, we see that -(i/\hbar)V_{mn}(t)\,dt corresponds to the amplitude for state n to transition to state m during time interval t\rightarrow t+dt, giving (eventually)
$$P(n\rightarrow m)=\frac{|V_{mn}|^2}{(E_m-E_n)^2}\left[4\sin^2\frac{(E_m-E_n)T}{2\hbar}\right],$$
as the probability that state n transitions to state m during time interval T due to a single scattering event. This is all fine.

Problem: Where I’m struggling is when they go on to talk about situations where the energy spectrum is continuous, defining \rho(E)\,dE as the distribution of states in the range of energy E to E+dE, and looking at the total probability of transition
$$P=\int P(n\rightarrow m)\rho(E_m)\,dE_m.$$
Assuming E_n and E_m to be similar, they simplify this integral by treating |V_{mn}| and \rho(E_m) as effectively constant, leading eventually to the claim (p151) “[...] we obtain the result that the probability for a transition to some state in the continuum is
$$P(n\rightarrow m) = \frac{2\pi}{\hbar}|V_{mn}|^2\rho(E_n)T$$
and that the energy in the final state is the same as the energy in the initial state.” (emphasis mine).

Again, the result of the integration is fine, but the statement about the energy in the two states seems to have come out of nowhere, and doesn’t seem (to me) to chime at all with the idea of the continuum of energy states. They go on to give the probability for a transition per unit time with a \delta(E_m-E_n) term, reinforcing the above statement, but again, I can’t see where it has come from. I’ve considered the possibility that the statement is subject to approximations, but the text leading up to this point has been quite deliberate about indicating where approximations have been made.

Can anyone shine some light?
 
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Interesting. I can see in your derivation of the photoelectric effect that the delta function arises from \sin^{(2)}(Tx)/x^{(2)} as T\rightarrow\infty. In the text, the quoted result comes from an integral like
$$\int \frac{\sin^2[(E_m-E_n)T/2\hbar]}{(E_m-E_n)^2}\,dE_m,$$
and noting that \int_{-\infty}^\infty[(\sin^2x)/x^2]\,dx=\pi the result follows. So I can see how this follows the form of your piece, and it suggests that the authors may have intended to take T\rightarrow\infty as you did. It seems odd that they would have elided this, as, like I said, they have been quite careful about that sort of thing in the text leading up to this point, but there we go.
 
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