Find Energy from canonical function

In summary, the partition function of a quantum rotor, Z=2T/s + 1/3 + s/(30T), leads to the result U=nk(T-s/6-s^2/(180T)) when expanded to second order in the small quantity s/T. This can be shown by factoring out 2T/s in the denominator and keeping the expansion to second order in the approximation 1/(1+x) = 1 - x.
  • #1
boddhisattva
10
0

Homework Statement



Let Z=2T/s + 1/3 + s/(30T) be the partition function of a quantum rotor at s/T->0. Show that

[itex]U=nk(T-s/6-s^2/(180T)[/itex]

Homework Equations



1/(1+x) = 1 -x

The Attempt at a Solution



[itex]U=-kT^2(\partial _{T} ln(Z) )[/itex]

Hence
[itex]U=-kT^2 [2/s - s/(30T^2)] / [ 2T/s + 1/3 + s/(30T) ][/itex]

I tried dividing upper and lower equation by 2T/s and use 1/(1+x) = 1 -x but cannot find the result.
 
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  • #2
boddhisattva said:
[itex]U=-kT^2(\partial _{T} ln(Z) )[/itex]
Are you sure the negative sign on the right side is correct?
[itex]U=-kT^2 [2/s - s/(30T^2)] / [ 2T/s + 1/3 + s/(30T) ][/itex]

Try factoring out 2T/s in the denominator.

Note that you want to get a result for U that is good to second order in the small quantity s/T.

So, you might need to include the next higher order in the approximation 1/(1+x) = 1 - x
 
  • #3
boddhisattva said:

Homework Statement



Let Z=2T/s + 1/3 + s/(30T) be the partition function of a quantum rotor at s/T->0. Show that

[itex]U=nk(T-s/6-s^2/(180T)[/itex]

Homework Equations



1/(1+x) = 1 -x

The Attempt at a Solution



[itex]U=-kT^2(\partial _{T} ln(Z) )[/itex]
I think that it should be [itex]U=nkT^2(\partial _{T} ln(Z) )[/itex]

Hence
[itex]U=-kT^2 [2/s - s/(30T^2)] / [ 2T/s + 1/3 + s/(30T) ][/itex]

I tried dividing upper and lower equation by 2T/s and use 1/(1+x) = 1 -x but cannot find the result.
I got their answer. You are doing it right but, as already pointed out, maybe you forgot to keep the expansion to second order, which you have to do here,
[itex] 1/(1-x) = 1 + x + x^2 + \ldots [/itex]
 

What is a canonical function?

A canonical function is a mathematical function that is used to describe a system or phenomenon in its simplest or most standard form. It is often used in physics and engineering to simplify complex systems and make calculations easier.

Why is it important to find energy from a canonical function?

Finding energy from a canonical function allows us to understand and analyze the energy behavior of a system. This can help in predicting the behavior of the system in different scenarios and making informed decisions.

How do you find energy from a canonical function?

To find energy from a canonical function, you need to use the appropriate mathematical equations and manipulate them according to the given function. This may involve solving for energy or using the function to calculate energy values at different points.

What types of systems can be described by a canonical function?

A variety of physical systems can be described by a canonical function, including mechanical, electrical, and thermal systems. Examples include a pendulum, an electric circuit, and a gas in a container.

Can a canonical function be used to describe complex systems?

Yes, a canonical function can be used to describe complex systems. However, in order to do so accurately, the function may need to be combined with other mathematical tools and techniques, such as differential equations and numerical methods.

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