Finding the State and Expectation Value for a Free Particle at Time t

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Homework Help Overview

The discussion revolves around finding the state and expectation value for a free particle at time t, specifically focusing on the time evolution of quantum states represented by momentum eigenstates. The original poster presents a mathematical expression for the state at time t and seeks assistance in computing the expectation value of the momentum operator.

Discussion Character

  • Exploratory, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • Participants discuss the time evolution of the state using the Hamiltonian operator and the momentum operator. There are questions about the correct notation and the handling of integrals in the expectation value calculation. Some participants express confusion regarding the normalization of momentum eigenstates and the implications of complex conjugates in the integrals.

Discussion Status

The discussion is ongoing, with participants providing clarifications on notation and mathematical expressions. There is a recognition of the need for accurate representation of operators and integrals, and some guidance has been offered regarding the structure of the expectation value calculation. Multiple interpretations of the problem are being explored.

Contextual Notes

Participants note potential confusion regarding the normalization of eigenstates and the assumptions made about the integrals involved in the expectation value. There are references to specific quantum mechanics texts for further clarification, indicating that the discussion is rooted in established theoretical frameworks.

spacetimedude
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Homework Statement


The eigenstates of the momentum operator with eigenvalue k are denoted by |k>, and the state of the system at t = 0 is given by the vector
|{ψ}>=\int \frac {dk}{2π} g(k)|{k}>
Find the state of the system at t, |ψ(t)>.

Compute the expectation value of \hat{P}.

Homework Equations

The Attempt at a Solution


From what I learned from the lecture, I just have to introduce (multiply) \exp[\frac{-i}{\hbar}\hat{H}t] where in this free particle case, \hat{H}=\frac{\hat{P}^2}{2m}, to |ψ>.

So |{ψ(t)}>=\exp[\frac{-i}{\hbar}\frac{\hat{P}^2}{2m}t]\int \frac {dk}{2π} g(k)|{k}>

When I compute for the expectation value using <ψ(t)|\hat{P}|ψ(t)>, I get \frac{1}{4\pi^2}\int |k|^2 \hat{P} dx.

The exponentials cancel due to multiplying of its complex conjugate.
I was confused on how to get rid of the two integrals with dk. I assumed (without reason so probably wrong) they become 1 because they are the product of complex conjugate and the total probability is 1.

Any help will be appreciated!

PS. How do I type ket in latex?
 
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Hi,

You want to be a bit more accurate.

For time development I think you want ##H## and not ##\hat H##. ##H## is an operator and yes, the ##|k>## are simultaneous eigenfunctions of H and p . See the link for the normalization: you don't have two integrals with ##k## but one with ##k## and one with ##k'##.

Equally, for ##\hat P## you want the operator ##\ p\ ## and not the number ##\hat P## (that would be kind of circular ...)

Ket in ##LaTeX## is just what you did. Or use \left \langle a\middle | b\right \rangle : ##\ \ \left \langle a\middle | b\right \rangle ##
 
BvU said:
Hi,

You want to be a bit more accurate.

For time development I think you want ##H## and not ##\hat H##. ##H## is an operator and yes, the ##|k>## are simultaneous eigenfunctions of H and p . See the link for the normalization: you don't have two integrals with ##k## but one with ##k## and one with ##k'##.

Equally, for ##\hat P## you want the operator ##\ p\ ## and not the number ##\hat P## (that would be kind of circular ...)

Ket in ##LaTeX## is just what you did. Or use \left \langle a\middle | b\right \rangle : ##\ \ \left \langle a\middle | b\right \rangle ##

Hmm, I'm a bit confused. From my understanding, ##\hat{H}=\hat{T}+\hat{U}## where ##\hat{T}## is the kinetic operator and ##\hat{U}## the potential operator. And for free particle, U=0. Then I wrote the kinetic energy operator in terms of the momentum operator.
Isn't ##\hat P## the operator ##-i \hbar \frac {d}{dx}## and not a number? And do you mean that when I take the complex conjugate of one of the ##Ψ(t)##, I should take the integral of k' and the other one in k, resulting in ##\frac{1}{4\pi^2}\int dk' g(k') \int dk g(k)## ? I don't know why I need to consider ##\hat{p}^2## because it gets canceled out when multiplying the complex conjugate of the exponential.
 
Sorry, my bad -- I wrongly interpreted your notation . So ##\hat P|k> = k |k>## . That way you can describe the time development of ##|k>##.
For the time development, the exponent therefore stays under the integral: each ##|k>## has its own time development.

spacetimedude said:
And do you mean that when I take the complex conjugate of one of the Ψ(t)Ψ(t)Ψ(t), I should take the integral of k' and the other one in k, resulting in
yes. see the link: the integration yields something with a delta function.
 
BvU said:
Sorry, my bad -- I wrongly interpreted your notation . So ##\hat P|k> = k |k>## . That way you can describe the time development of ##|k>##.
For the time development, the exponent therefore stays under the integral: each ##|k>## has its own time development.

yes. see the link: the integration yields something with a delta function.

Not quite sure how to follow the steps on the link. The integral I have for the expectation is ##\frac {1}{(2\pi)^2}\int dx \int dk \int g(k')g(k)k'k(dk')##. Have I done something wrong?
 
Where are the ##\ \ \left \langle k'\middle | k \right \rangle \ \ ##? ##\quad## And the operator only works to the right, doesn't it ?
 
BvU said:
Where are the ##\\\ \left \langle k'\middle | k \right \rangle \ \ ##? ##\quad## And the operator only works to the right, doesn't it ?
Hmm, is it supposed to be ##<k'| \frac{1}{2\pi} \int dk' g(k') \exp{\frac{i\hat P ^2 t}{2m\hbar}} \int \hat P \frac{1}{2\pi}dk g(k) \exp{\frac{-i\hat P^2t}{2m\hbar}}|k>## then the exponentials cancel so ##<k'| (\frac{1}{2\pi})^2 \int dk' g(k') \ \int \hat P dk g(k)|k>##? Do I then compute for the expected value using the method of integrating the products of the complex conjugate of <k'|..., ##\hat P## and ...|k>?

Becomes ##\frac{1}{4\pi^2}\int dx k'^* [\int \int dk'dk \hat P g(k')g(k)k]##
 
Last edited:
I also wonder how you can end up with a triple integral
Did you find the normalization eqn for the momentum eigenstates in the link ?
 
Note that for ##<p>## (expectation value for ##\hat p## ), you want to end up somewhere at ##\ \int k\;|g(k)| ^2\;dk\ ## (according to my Merzbacher, QM, ##\ |g(k)| ^2 ## is the probability density in momentum space)
 

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