Finite Square Well: Deriving Eq. (1)

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SUMMARY

The discussion focuses on the derivation of Equation (1) from Griffiths' Quantum Mechanics regarding the Finite Square Well, specifically in the context of bound states where energy E is less than zero. The equation in question is tan z = √((z₀/z)² - 1), with z₀ = (a/ħ)√(2mV₀) and l = √(2m(E + V₀))/ħ. The claim made is that for large values of z₀, the intersections of the curves occur just below zₙ = nπ/2 for odd n, leading to the approximation Eₙ + V₀ ≈ (n²π²ħ²)/(2m(2a)²). The reasoning is that large z₀ results in solutions for z that approximate nπ/2.

PREREQUISITES
  • Understanding of Quantum Mechanics principles, particularly bound states.
  • Familiarity with Griffiths' Quantum Mechanics textbook.
  • Knowledge of trigonometric functions and their properties.
  • Basic proficiency in mathematical plotting software, such as Mathematica.
NEXT STEPS
  • Study the derivation of bound state energies in the Finite Square Well potential.
  • Learn about the implications of large parameters in quantum mechanics, specifically in potential wells.
  • Explore the use of Mathematica for visualizing mathematical functions and their intersections.
  • Investigate the behavior of the tangent function and its applications in quantum mechanics.
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Students and researchers in quantum mechanics, particularly those studying potential wells and bound states, as well as educators looking to clarify complex derivations in quantum theory.

Bashyboy
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Hello everyone,

I am reading about the Finite Square Well in Griffiths Quantum Mechanics Text. Right now, I am reading about the case in which the particle can be in bound states, implying that it has an energy E < 0. After some derivations, the author comes across the equation

\tan z = \sqrt{ \left(\frac{z_0}{z} \right)^2 - 1}

where z = la and z_0 = \frac{a}{\hbar} \sqrt{2mV_0}; additionally, l= \frac{\sqrt{2m(E+V_0)}}{\hbar}.

The author makes the claim that, "if z_0 is very large, the intersections occur just slightly below z_n = n \frac{\pi}{2}, with n odd; it follows that

E_n + V_0 \approx \frac{n^2 \pi^2 \hbar^2}{2m(2a)^2}" (1)

I don't quite see this. How does z_0 being large imply (1) is a true statement? I have tried to work out the details myself, but it appears that there are a lot of missing details which the author should have included; although, this is just my opinion.
 
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It seems very straightforward to me. ##\frac{n\pi \hbar}{2a} \approx \sqrt{2m(E + V_0)}## so ##E + V_0 \approx \frac{n^2 \pi^2 \hbar^2}{2m(2a)^2}##. ##z_0## being very large implies that the solutions ##z## to ##\tan z = \sqrt{(z_0/z)^2 - 1}## are ##z = \frac{n\pi}{2}##. Just make a plot of the two curves on mathematica for large ##z_0## and it should be obvious to you why the intersections are as they are for large ##z_0##.
 

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