Finite Well and Schrodinger's Equation

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SUMMARY

The discussion centers on solving Schrödinger's Equation for an electron trapped in a finite potential well with a width of 0.5 nm and a depth of 50 eV. The participants focus on calculating the wave number \( k \) using the formula \( k = \sqrt{\frac{2m}{\hbar^2}(U-E)} \), where \( U \) is the potential energy, \( E \) is the energy of the electron, and \( \hbar \) is the reduced Planck's constant. Discrepancies in the calculated values of \( k \) arise due to potential miscalculations involving the constants and their units. The correct interpretation of \( \hbar \) and ensuring proper squaring of constants are critical for accurate results.

PREREQUISITES
  • Understanding of Schrödinger's Equation and quantum mechanics
  • Familiarity with finite potential wells and their properties
  • Knowledge of quantum mechanical constants, specifically Planck's constant and its reduced form
  • Ability to perform calculations involving square roots and unit conversions
NEXT STEPS
  • Review the derivation of Schrödinger's Equation in finite potential wells
  • Learn about the implications of wavefunctions in quantum mechanics
  • Study the concept of probability density in quantum systems
  • Explore the differences between Planck's constant \( h \) and the reduced Planck's constant \( \hbar \)
USEFUL FOR

Students and educators in quantum mechanics, particularly those studying wavefunctions and potential wells, as well as anyone involved in advanced physics problem-solving.

yayz0rs
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Homework Statement


An electron is trapped in a finite well of width 0.5 nm and depth of 50 eV. The wavefunction is symmetric about the center of the well (x = 0.25 nm). If the electron has energy 29.66 eV and ψ(0) = 1.42 (nm)-1/2, then what is the probability for finding the particle in the left half of the well (0 < x < 0.25 nm)?


Homework Equations


Schrödinger's Equation in the classically forbidden zone: C1ekx + C2e-kx

The Attempt at a Solution


My idea was that because the probability density from negative infinity to .25 nm (L/2) would be .5, I could simply find p(<0) by integrating Schrödinger's equation and subtracting that from .5. However I cannot find K.

I know the equation for K is [tex]\sqrt{2m/(h/2\Pi)^2(U-E)}[/tex] and it seems like I've been given those 4 variables. However my homework will not accept my answer for K. For reference I've been getting k = 9.25 nm^-1.
 
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Hello yayz0rs,

Welcome to Physics Forums.

I'm getting a different answer for k.

My solution to Shrodinger's equation in that region matches yours (at least involving k). There's nothing wrong with your equation for k, as far as I can tell. But still I'm getting a different value than yours when calculating the number.

For your reference, your value for k is different from mine by close to a factor of [tex]\sqrt{2 \pi}[/tex]. Are you sure you are squaring the [tex]2\pi[/tex] along with the h? Are you making sure to use the correct value for h (as opposed to [tex]\hbar[/tex] which as the [tex]2 \pi[/tex] already factored in)?
 
By the way, your equation, as it is written, could use a little clarity by adding parenthesis or something appropriately. In my last post, above, I assume your equation really means

[tex]k = \sqrt{\frac{2m}{\hbar^2}(U-E)}[/tex]

where

[tex]\hbar = \frac{h}{2\pi}[/tex]

in which case, we both got the same equation for k.
 

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