Typically yes, these are called static and kinetic friction coefficients. It's just like anything really. Try to move a couch across your floor. Once you get it moving you don't want to let it stop because its hardest to "get it going".
When looking at a force applied vs friction plot, (see http://www.roymech.co.uk/images11/friction.gif ) the friction force will increase linearly with the applied force until the object "breaks loose". At this point, the frictional force will be constant regardless of force applied. This frictional force is then used to compute the kinetic coefficient of friction.
The peak, or point 'just' before the object breaks loose is the highest friction force. It's used for the static coefficient. Typically the values can vary quite a bit (think back to your couch).