Free particle: expectation of x for all time with Ehrensfest

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Homework Help Overview

The discussion revolves around a quantum mechanics problem involving a free particle in one dimension, described by a Hamiltonian and a specific wavefunction. The original poster seeks to determine the expectation value of the particle's position over time using Ehrenfest's theorem.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to apply Ehrenfest's theorem to find the time evolution of the expectation value of position. Some participants question the validity of commutation relations and suggest verifying assumptions regarding the operators involved. Others explore the implications of classical definitions of momentum and velocity in relation to the problem.

Discussion Status

Participants are actively engaging with the mathematical framework of the problem, discussing the application of Ehrenfest's theorem and the properties of operators. There is a recognition of the need to clarify the relationship between the derived expressions and the expectation value over time. Some guidance has been offered regarding the use of commutation relations and classical definitions, but no consensus has been reached on the final approach.

Contextual Notes

Participants are navigating the complexities of quantum mechanics, particularly the interpretation of operators and their time evolution. There is an acknowledgment of the challenge in finding the expectation value for all later times, with some expressing uncertainty about the steps needed to achieve this.

renec112
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Hello physics forums. I'm trying to solve an old exam question. Would love your help.

Homework Statement


A free particle in one dimension is described by:
## H = \frac{p^2}{2m} = \frac{\hbar}{2m}\frac{\partial^2}{\partial x^2}##

at ##t = 0##
The wavefunction is described by:
## \Psi(x,0) = N(a^2-x^2) e^{i k x}## for ##|x| \leq a##
outside ##a##, ## \Psi = 0##. Use Ehrenfest to find the expectation value for all later times ##<x(t))>## of the particles position for all time ## t \geq 0 ##.

Homework Equations


Ehrensfest:
##
\frac{d<Q>}{dt} = \frac{i}{\hbar}<[H,Q]> + <\frac{\partial Q}{\partial t}>
##
Where ##Q## is an operator.

The Attempt at a Solution


We need to find it for all later times, Ehrensfest will show how an operator evolves in time. So set ##Q = x## and use Ehrenfest. Then we know the poisiton for all later time.
##
\frac{d<x>}{dt} = \frac{i}{\hbar}<[H,x]> + <\frac{\partial x}{\partial t}>
##
Since the operator does not change in time we have:
##
\frac{d<x>}{dt} = \frac{i}{\hbar}<[H,x]>
##
Here is where i am stuck. I am trying to do the commutator:
##
\frac{d<x>}{dt} = \frac{i}{\hbar}<(Hx -xH>
##
However, these do commute and hence everything should be zero.

What do you think?
 
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renec112 said:
However, these do commute ...
Can you show that this is true?
 
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kuruman said:
Can you show that this is true?
Actually when you say it like that..
I guess i thought in
## H = \frac{p^2}{2m} = \frac{\hbar}{2m}\frac{\partial^2}{\partial x^2}##
the ##p## is just a constant but off course it's an operator:
##p = i \hbar \frac{\partial}{\partial x}##

I guess the only thing to do is to differentiate a couple of times and then take the inner product :D

##
\frac{d<x>}{dt} = \frac{i}{\hbar}<Hx -xH>
##
##
= \frac{i}{\hbar}<\frac{\hbar}{2m}\frac{\partial^2}{\partial x^2} x -x\frac{\hbar}{2m}\frac{\partial^2}{\partial x^2}>
##
##
= < \Psi | \frac{i}{\hbar}<\frac{\hbar}{2m}\frac{\partial^2}{\partial x^2} x -x\frac{\hbar}{2m}\frac{\partial^2}{\partial x^2} | \Psi>
##

Seems legit?

Thank you for helping me.
 
It's legit, but you need to advance it further. Remember that ##[x,p_x] = i \hbar##. There is also a useful identity about commuting operators, that says$$[AB,C]=A[B,C]+[A,C]B.$$ Prove it then use it. What do you think ##A##, ##B## and ##C## should be identified as?
 
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kuruman said:
It's legit, but you need to advance it further. Remember that ##[x,p_x] = i \hbar##. There is also a useful identity about commuting operators, that says$$[AB,C]=A[B,C]+[A,C]B.$$ Prove it then use it. What do you think ##A##, ##B## and ##C## should be identified as?
Oh I see. That's very smart.
This is what i did:
##\frac{d<x>}{dt} = \frac{i}{\hbar} <[H,x]>##
insert hamilton
##= \frac{i}{\hbar} <[P^2/2m,x]>##
##= \frac{i}{2 m \hbar } <[PP,x]>##
##= \frac{i}{2 m \hbar } <P[P,x]+[P,x]P>##
##= \frac{i}{2 m \hbar } <-P[x,P]-[x,P]P>##
##= \frac{i}{2 m \hbar } <-P i \hbar-P i \hbar>##
##= \frac{1}{m} <P>##

And i already calculated ##<P>## from another task.
Not sure if it's correct, but it feels like it. Thank you very much for helping me out :) !
 
renec112 said:
Not sure if it's correct, but it feels like it.
Classically, what is v in terms of p?
 
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kuruman said:
Classically, what is v in terms of p?
## v = \frac{1}{2} m v^2##
## = \frac{m^2v^2}{2m}##
## = \frac{p^2}{2m}##
## \Rightarrow p = \sqrt{2 v m}##
Like this?
 
renec112 said:
## v = \frac{1}{2} m v^2##
## = \frac{m^2v^2}{2m}##
## = \frac{p^2}{2m}##
## \Rightarrow p = \sqrt{2 v m}##
Like this?
Nope. To begin with, ##\frac{1}{2}mv^2## is kinetic energy ##K##, not speed. What is the classical definition of momentum? Look it up if you forgot.
 
Last edited:
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kuruman said:
Nope. To begin with, ##\frac{1}{2}mv^2## is kinetic energy ##K##, not speed. What is the classical definition of momentum? Look it up if you forgot.
Thanks for helping me :)
Its ##p = mv## off course.
Oh i so the m' cancels and i am left with only ##<x>##... Nice trick ! Thank you :)
 
  • #10
renec112 said:
Thanks for helping me :)
Its ##p = mv## off course.
Oh i so the m' cancels and i am left with only ##<x>##... Nice trick ! Thank you :)
Not so fast. So far, you have established that ##\frac{d<x>}{dt}=<v>=\frac{1}{m}<p>##. You have not found ##<x>##.
 
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  • #11
kuruman said:
Not so fast. So far, you have established that ##\frac{d<x>}{dt}=<v>=\frac{1}{m}<p>##. You have not found ##<x>##.
Oh right.. I think i misunderstood the question then.
I need to find ##< x(t)> ## for all later times.
But i can't see, how i can find that.. You are saying ##\frac{d<x>}{dt} \neq < x(t)> ##

I am not sure why i should fine ##< x >## I can see it's a part of the equation, but why does it give me ##<x(t)>## for all later times?

I only know how to find ##<x>## when ##t = 0##. Then it's just: ##< \Psi(x,0) | x | \Psi(x,0)>##

Thank you for the comment! appreciate it :)
 

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