To preserve reactions rates, you want to collapse the cross sections by "flux weighting" them.
You didn't mention what groups collapse to other groups, but assume you want to collapse the first two cross sections in the 4-group structure down to the first group in the 2-group structure.
$$\overline{\Sigma_{x1}} = \frac{ \Sigma_{x1} \phi_1 + \Sigma_{x2} \phi_2}{\phi_1 + \phi_2} $$
Likewise, collapsing the second two cross sections in the 4-group structure to the second group in the 2-group structure
$$\overline{\Sigma_{x2}} = \frac{ \Sigma_{x3} \phi_3 + \Sigma_{x4} \phi_4}{\phi_3 + \phi_4} $$
where:
* The LHS is in the two-group structure,
* The RHS is in the four-group structure, and
* ##x## is the type of reaction (absorption, fission, etc.)
The scattering cross sections are a little more complicated.
$$\overline{\Sigma_{1\rightarrow1}} = \frac{ \Sigma_{1\rightarrow1} \phi_1 + \Sigma_{1\rightarrow2} \phi_1 + \Sigma_{2\rightarrow1} \phi_2 + \Sigma_{2\rightarrow2} \phi_2}{\phi_1 + \phi_2} $$
etc. for ##\overline{\Sigma_{1\rightarrow2}}##, ##\overline{\Sigma_{2\rightarrow1}}##, and ##\overline{\Sigma_{2\rightarrow2}}##
These equations only accounts for energy, it doesn't include any spatial dependence to the cross sections.
There is a more general formula that includes energy and space, but it is difficult to write in this forum..