Gravimetric Analysis with empirical formula

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Discussion Overview

The discussion revolves around a homework problem involving gravimetric analysis to determine the empirical formula of a cobalt-iodine compound based on the mass of silver iodide (AgI) produced from a reaction with silver nitrate (AgNO3). The focus is on the stoichiometry of the reaction and the calculations required to derive the empirical formula from the given data.

Discussion Character

  • Homework-related
  • Mathematical reasoning

Main Points Raised

  • One participant presents a problem statement involving a 3.500 g sample of cobalt and iodine, leading to the formation of 5.255 g of AgI.
  • Another participant suggests using the 1:1 mole ratio for the reaction between AgNO3 and the iodide ion to determine the moles of iodide precipitated.
  • A question is raised about whether the moles of AgNO3 need to be calculated to establish the mole ratio and seeks clarification on which iodide is being referred to.
  • It is clarified that AgNO3 was in excess, indicating that the exact amount of AgNO3 is not necessary for the calculations.

Areas of Agreement / Disagreement

Participants appear to agree on the need to establish the mole ratio of iodide to cobalt but have not reached consensus on the specific calculations or the necessity of determining the moles of AgNO3.

Contextual Notes

Participants have not fully resolved the steps needed to calculate the empirical formula, and there are uncertainties regarding the calculations of moles and the definitions of the components involved.

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Homework Statement


a 3.500 g sample of a compound of cobalt and iodine was dissolved in water and treated with excess AgNO3 solution producing 5.255g AgI. Determine the empirical formula.

A clearer view of the question:http://www.chem.mun.ca/courseinfo/c1050/Louise_Dawe/Basic%20Chemical%20Concepts%20I.pdf"

question # 20.





The Attempt at a Solution


I started by getting the mole of AgI and making a mole to mole ratio with CoxIy...and I'm not sure if what I did was right.
Thanks
 
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You do not yet know the mole ratios or atom ratios of the I to the Co. First use the 1:1 mole ratio for the reaction of AgNO3 to the Iodide ion. How many moles of Iodide were precipitated? That gives you the number of moles of I from the sample of the cobalt-iodine compound. Convert to grams; find the grams of cobalt by difference, since you know how much sample you used.
 
Do I need to find the moles of AgNO3 to find the 1:1 mole ratio? or get the moles of AgI from it's mass 5.255g? and to which Iodide are you referring to?

Thanks
 
AgNO3 was in excess to ensure all iodine has been precipitated as AgI (silver iodide). Exact amount of AgNO3 doesn't matter.
 

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