Hamiltonian for a dimer approaching a surface

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SUMMARY

The discussion focuses on deriving the Hamiltonian for a dimer approaching a surface, emphasizing the fixed angle between the surface and the dimer while neglecting angular momentum. The kinetic energy term is derived from two masses parallel to the surface by separating center of mass and relative coordinates. The user seeks guidance on the derivation process and potential starting points for this problem.

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  • Knowledge of polar and azimuthal coordinates
  • Basic concepts of angular momentum in physics
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AllenFaust
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Hi! it's been a day since I have started this problem. I was wondering how I could arrive to this Hamiltonian?
And I'm a bit at a lost on how exactly to derive this? I hope anyone can help me with this, even a suggestion of good starting point would be much appreciated.

upload_2017-6-9_18-1-7.png


Basically the problem is to derive a hamiltonian for the system here.
upload_2017-6-9_18-2-6.png


Regarding this, I'm currently thinking of having a set of polar and azimuthal terms cancel out and thus leading to this maybe?

Thank you very much!
 

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The model appears to assume that the angle between the surface and the dimer is fixed, and neglects angular momentum. The kinetic energy term can be derived starting from two masses parallel to the surface, then separating out center of mass and relative coordinates.
 

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