Help with Schoedinger´s equation when V(x)=0

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Discussion Overview

The discussion revolves around solving Schrödinger's equation for the case where the potential V(x) is zero. Participants explore the implications of this scenario on wave functions, phase velocity, and group velocity, while also comparing concepts from quantum mechanics and classical wave theory.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant presents a solution to Schrödinger's equation with specific parameters, noting a discrepancy in phase velocity.
  • Another participant clarifies the distinction between phase velocity and group velocity, providing relevant formulas.
  • There is a question regarding the correct form of the relationship between energy and frequency, with some confusion expressed about the group velocity in the context of a single frequency.
  • Participants discuss the analogy between quantum wave functions and classical wave equations, particularly regarding dispersion relations.
  • One participant suggests that group velocity can be thought of as describing "particle-like" properties, while phase velocity describes "wave-like" properties, though this is noted to be a heuristic interpretation.

Areas of Agreement / Disagreement

Participants generally agree on the definitions and relationships between phase and group velocity, but there remains some uncertainty regarding the implications of these concepts in different contexts, particularly in relation to single frequency components and classical analogies.

Contextual Notes

There are unresolved questions about the application of group velocity in scenarios with only one Fourier component and the differences in dispersion relations between quantum mechanics and classical wave equations.

Who May Find This Useful

This discussion may be useful for students and enthusiasts of quantum mechanics, wave theory, and those interested in the conceptual connections between classical and quantum physics.

DaTario
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Hi All,

I have tried to solve Schroedinger´s equation for the case where ##V(x) = 0## for a particle with ##m=0.5## and ##v_0 = 2##. This yields ##E = 1## and ##p=1##.
From the fundamental relations of De Broglie and Planck, ##k = 1/ \hbar ## and ##\omega = 1/\hbar ##.
Thus, I have confirmed that the function ##\Psi(x,t) = e^{i(x - t)/\hbar} ## is a solution of the Schroedinger's equation. Surprisingly the phase velocity of this wave function is not ##2\, m/s## but ##1\, m/s##.
What have gone wrong ?

Best wishes,
DaTario
 
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Nothing is wrong. For waves one can introduce two different velocities, namely phase velocity
$$v_p=\frac{\omega}{k}$$
and group velocity
$$v_g=\frac{\partial\omega}{\partial k}$$
For ##V(x)=0## one has ##\omega=\hbar k^2/2m##, so in your case ##v_g=2## and ##v_p=1##. To check this, be careful to compute ##\partial\omega/\partial k## before you put in a specific value of ##k##.
 
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Ok. First, thank you. But two comments follows:

1) would it be ## \omega = \hbar^2 k^2/2m ## ?

2) I had some difficulty in thinking of group velocity having only one "Fourier" component. How this works with only one frequency present?
 
DaTario said:
1) would it be ## \omega = \hbar^2 k^2/2m ## ?
No, because ## E = \hbar^2 k^2/2m ## and ##\omega=E/\hbar##.

DaTario said:
2) I had some difficulty in thinking of group velocity having only one "Fourier" component. How this works with only one frequency present?
I'm not sure what confuses you, but perhaps your question is answered by the fact that here we consider only one space dimension with coordinate ##x##.
 
Ok, sorry with 1).

But wrt 2), this situation still resembles that one where we have a wave function (from the wave equation context) like ##\sin(kx - \omega t)##. Do we have here (in the context of a wave on a string) also a group velocity? It is equal to the phase velocity in this case, as it seems?
Is it correct to say that ##ω=ℏk^2/2m## is the dispersion relation and it is different from the one which is present in solving the wave equation (##\omega = k v##)?
 
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DaTario said:
But wrt 2), this situation still resembles that one where we have a wave function (from the wave equation context) like ##\sin(kx - \omega t)##. Do we have here (in the context of a wave on a string) also a group velocity?
Of course.

DaTario said:
It is equal to the phase velocity in this case, as it seems?
For the simplest classical string dispersion relation is of the form ##\omega=vk##, so group velocity is equal to the phase velocity.

DaTario said:
Is it correct to say that ##ω=ℏk^2/2m## is the dispersion relation and it is different from the one which is present in solving the wave equation (##\omega = k v##)?
Yes.
 
Note also that the group velocity formula
$$v_g=\frac{\partial\omega}{\partial k}$$
is closely related to the formula for velocity of a particle in classical Hamiltonian mechanics
$$\dot{x}=\frac{\partial H}{\partial p}$$
Hence, loosely speaking, it can be said that group velocity describes "particle-like" properties, while phase velocity describes "wave-like" properties. (Heuristically this makes sense in the context of quantum mechanics, but should not be taken too literally.)
 
Demystifier said:
Note also that the group velocity formula
$$v_g=\frac{\partial\omega}{\partial k}$$
is closely related to the formula for velocity of a particle in classical Hamiltonian mechanics
$$\dot{x}=\frac{\partial H}{\partial p}$$
Hence, loosely speaking, it can be said that group velocity describes "particle-like" properties, while phase velocity describes "wave-like" properties. (Heuristically this makes sense in the context of quantum mechanics, but should not be taken too literally.)

Beautiful connection, in deed.

Thank you very much, Demystifier. I think now the entropy of the concepts inside my brain has decreased considerably.
 
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DaTario said:
I think now the entropy of the concepts inside my brain has decreased considerably.
Which, by the second law of thermodynamics, considerably increased entropy in your brain's environment. :biggrin:

For further decrease of your brain's entropy you might be interested in my paper https://arxiv.org/abs/quant-ph/0609163
 
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If the thermodynamical consequence is only heat produced in the surroundings of my brain, attending to a nice explanation session, like this was, in a cold day may represent winning in both sides.

Thank you for sending me the link of your paper.
Best wishes.
 
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