Is the Momentum Operator Hermitian in Quantum Mechanics?

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SUMMARY

The momentum operator in quantum mechanics, defined as -i(h bar)d/dx, is not strictly Hermitian but is self-adjoint. The distinction arises because while Hermitian operators satisfy A = A(dagger), the momentum operator's derivative component is anti-Hermitian. This leads to real eigenvalues and expectation values, but the eigenfunctions are not normalizable within the Hilbert space. Understanding the self-adjointness of the momentum operator requires examining the inner product definitions and integration by parts.

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  • Understanding of Hermitian and self-adjoint operators in quantum mechanics
  • Familiarity with the momentum operator and its mathematical representation
  • Knowledge of inner product spaces and integration techniques
  • Basic principles of quantum mechanics and wave functions
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  • Study the concept of self-adjoint operators in quantum mechanics
  • Learn about the implications of anti-Hermitian operators
  • Explore the integration by parts technique in the context of quantum mechanics
  • Review quantum mechanics textbooks such as Ballentine and Griffiths for deeper insights
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Quantum mechanics students, physicists, and researchers interested in the mathematical foundations of quantum operators and their properties.

dyn
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A Hermitian operator A is defined by A=A(dagger) which is the transpose and complex conjugate of A. In 1-D the momentum operator is -i(h bar)d/dx. How can this be Hermitian as the conjugate has the opposite sign ?
Thanks
 
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dyn said:
A Hermitian operator A is defined by A=A(dagger) which is the transpose and complex conjugate of A. In 1-D the momentum operator is -i(h bar)d/dx. How can this be Hermitian as the conjugate has the opposite sign ?
For unbounded operators with infinite spectrum, such as the momentum operator, one should use the adjective "self-adjoint" instead of Hermitian. If ##\phi, \psi## are square-integrable wave-functions, then a linear operator ##A## is said to be self-adjoint if
$$\int\!dx\; \phi^*(x) \, A \psi(x) ~=~ \int\!dx \Big(A \phi(x)\Big)^* \, \psi(x) ~.$$Exercise: check whether the above holds when ##A## is the momentum operator. :biggrin:
(Hint: use integration by parts.)
 
So the momentum operator isn't Hermitian ? But it still returns real eigenvalues and expectation values. Does it also produce orthogonal wavefunctions ?
 
dyn said:
A Hermitian operator A is defined by A=A(dagger) which is the transpose and complex conjugate of A. In 1-D the momentum operator is -i(h bar)d/dx. How can this be Hermitian as the conjugate has the opposite sign ?
Thanks

Checking whether ##A = A^\dagger## isn't quite as easy as it looks: the derivative operator ##\frac{d}{dx}## is in fact anti-Hermitian, so that the momentum operator as a whole is Hermitian (unsophisticated people like myself treat "Hermitian" and "self-adjoint" as synonyms, though in reality as strangerep points out this ignores certain subtleties).

"##A = A^\dagger##" is basically shorthand for the expression strangerep wrote. You should check whether that expression holds when ##A## is the momentum operator. If it holds, then the momentum operator is Hermitian.
 
dyn said:
So the momentum operator isn't Hermitian ? [...]
The notion of self-adjointness is a generalization of the notion of Hermiticity. E.g., in a finite dimensional vector, where ##u,v## are vectors (with complex components), the usual inner product can be written as
$$ (u,v) ~:=~ u^\dagger v ~.$$ If ##A## is a matrix, it is self-adjoint if ## (Au, v) = (u,Av)## or in this case:$$u^\dagger A v ~=~ (Au)^\dagger v ~.$$Thus, self-adjointness coincides with Hermiticity in the finite-dimensional case, i.e., is equivalent to usual notion of Hermiticity as the transpose conjugate.

Expressing the notion in terms of the inner product allows it to be generalized to infinite-dimensional Hilbert spaces of wave functions, on which the momentum operator acts. In that case, Hermiticity and self-adjointness no longer coincide, in general. Self-adjointness still guarantees real eigenvalues (exercise).

As for orthogonality of eigenfunctions, the concept of eigenfunction must be generalized since those of the momentum operator are not normalizable, hence not in the Hilbert space. But that's a long story.

What textbook(s) are you studying from? I.e., QM and linear algebra? If you don't have any, then try Ballentine for QM and maybe Axler for linear algebra.
 
strangerep said:
For unbounded operators with infinite spectrum, such as the momentum operator, one should use the adjective "self-adjoint" instead of Hermitian. If ##\phi, \psi## are square-integrable wave-functions, then a linear operator ##A## is said to be self-adjoint if
$$\int\!dx\; \phi^*(x) \, A \psi(x) ~=~ \int\!dx \Big(A \phi(x)\Big)^* \, \psi(x) ~.$$

Isn't this hermitian? In order to be self-adjoint, you need some subtleties with the domain to hold.
 
micromass said:
Isn't this hermitian? In order to be self-adjoint, you need some subtleties with the domain to hold.
Ssshh. I was trying to coax the OP away from the notion of transpose+conjugate, and think in terms of the inner product instead in order to generalize to inf-dim spaces. I had intended (perhaps) to mention domains later, but let's wait and see what textbook(s) the OP is using, and what level of answer is appropriate... :biggrin:
 
strangerep said:
Ssssh. I was trying to coax the OP away from the notion of transpose+conjugate, and think in terms of the inner product instead in order to generalize to inf-dim spaces. I had intended (perhaps) to mention domains later, but let's wait and see what textbook(s) the OP is using, and what level of answer is appropriate... :biggrin:

Fair enough :-p Just found it weird that you corrected hermitian by self-adjoint but then write the condition for hermitian anyway. But yeah, let's wait for the OP to come back.
 
micromass said:
Fair enough :-p Just found it weird that you corrected hermitian by self-adjoint but then write the condition for hermitian anyway.
I'll rethink my pedagogical technique in future. :blushing:
 
  • #10
strangerep said:
I'll rethink my pedagogical technique in future. :blushing:

Don't, I'm just nitpicking :shy:
 
  • #11
I am mainly studying from QM textbooks. They all seem to say that the momentum operator is Hermitian and I can see that it satisfies the equations you have mentioned but I couldn't see how it satisfied A=A(dagger).
 
  • #12
dyn said:
I am mainly studying from QM textbooks. They all seem to say that the momentum operator is Hermitian and I can see that it satisfies the equations you have mentioned but I couldn't see how it satisfied A=A(dagger).

Take a look at strangerep's post #2. Do you agree that you need to check that relation for ##A##? Why don't you plug in your ##A## in that integral and work it out?
 
  • #13
dyn said:
I am mainly studying from QM textbooks. They all seem to say that the momentum operator is Hermitian and I can see that it satisfies the equations you have mentioned but I couldn't see how it satisfied A=A(dagger).
I agree with Micromass. It's time for you to do some work. (You couldn't even be bothered to say which textbooks.)
 
  • #14
dyn said:
I am mainly studying from QM textbooks. They all seem to say that the momentum operator is Hermitian and I can see that it satisfies the equations you have mentioned but I couldn't see how it satisfied A=A(dagger).

As others have said, the way to understand this is by looking at the definition of A^\dagger for inner products, which means an integral.

For the special case of A = \frac{d}{dx}, we have:

\int \Psi^*(x) \frac{d}{dx} \Phi(x) dx = \int \frac{d}{dx}(\Psi^*(x) \Phi(x)) dx - \int (\frac{d}{dx} \Psi^*(x)) \Phi(x) dx

That's just using the product rule for derivatives. The first term on the right vanishes for sufficiently well-behaved functions \Psi and \Phi, when we integrate over the entire space, so we have:

\int \Psi^*(x) \frac{d}{dx} \Phi(x) dx = - \int (\frac{d}{dx} \Psi^*(x)) \Phi(x) dx

That minus sign on the right is what makes \frac{d}{dx} anti-hermitian.
 
  • #15
strangerep said:
I agree with Micromass. It's time for you to do some work. (You couldn't even be bothered to say which textbooks.)

I am using a variety of textbooks including Shankar , Rae , Griffiths , Mandl and Zettilli
 

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