Hexagonal Closest Packed Unit Cell Height

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SUMMARY

The discussion focuses on deriving the height of a hexagonal closest packed unit cell as a function of the sphere radius (R). Key insights include the relationship between the basal plane's equilateral triangles and the positioning of atoms in the middle plane. The formula derived utilizes Pythagorean theorem to establish the height (h) in relation to the radius and packing efficiency, with the final equation being (2R)^2 = (c/2)^2 + (dist. calculated in #2)^2. The volume of the hexagonal unit cell is also calculated based on the number of spheres contributing to the packing.

PREREQUISITES
  • Understanding of hexagonal closest packing (HCP) structure
  • Familiarity with Pythagorean theorem applications
  • Knowledge of equilateral triangle properties and centroid calculations
  • Basic concepts of packing efficiency in crystallography
NEXT STEPS
  • Explore the derivation of height in face-centered cubic (FCC) structures
  • Study the mathematical properties of equilateral triangles and centroids
  • Investigate the implications of packing efficiency on crystal structures
  • Learn about 3D visualization tools for atomic structures, such as VESTA or CrystalMaker
USEFUL FOR

Chemists, materials scientists, and physicists interested in crystallography and atomic packing theories will benefit from this discussion.

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My attempts to derive the height as a function of radius of the spheres packing the unit cell have failed. The best attempt so far was to create a diagonal line from the top atom to one of the middle ones. With that distance I thought I could use trig to find the component parallel to the height and multiply by two. Of course that didn't work. Any hints or suggestions? Even good 3d visualizations would help.
 
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The trick is in realizing that the middle plane of atoms occupy positions directly above the centroids of the triangles in the base plane. This follows directly from a symmetry argument.

#1. Each basal plane has nearest neighbor atoms making equilateral triangles. So, a=2R (where R is the sphere radius).

#2. Each atom at height c/2 above the basal plane is positioned directly above the centroid of the triangles in the base plane. For an equilatreral triangle, the distance from a vertex to the centroid is two-thirds the length of the median.

#3. Each atom in the base plane has a nearest neighbor in this middle plane. So, the distance from the corner atom in the base plane to the nearby atom in the mid-plane is 2R.

#4. Finally, use Pythagoras to write (2R)^2 = (c/2)^2 + (dist. calculated in #2)^2. That should take you to the required ratio.
 
I tried to find it with the help of packing efficiency (i.e. 0.74). the number of contributing spheres inside one unit cell is 6. therefore volume of 6 spheres/volume of hexagonal unit cell=0.74
volume of hexagonal unit cell is 6*sqrt(3)*r*r*h
then u will get answer of "h".
 
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