Is Hexane Soluble in Crude Oil?

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Discussion Overview

The discussion centers around the solubility of hexane in crude oil, exploring the chemical composition of crude oil and the interactions between hydrocarbons. Participants examine whether hexane can dissolve in crude oil and the implications of distillation processes.

Discussion Character

  • Exploratory
  • Debate/contested
  • Technical explanation

Main Points Raised

  • Some participants suggest that hexane dissolves in fats and some oils, questioning if this applies to crude oil as well.
  • Others inquire about the types of compounds present in crude oil and their relationship to hexane.
  • It is noted that hexane is isolated from crude oil through distillation, implying that if hexane could dissolve in crude oil, distillation would not be effective for separation.
  • Some participants argue that crude oil is a solution of various hydrocarbons, and that miscibility is a prerequisite for solution, raising questions about hexane's solubility.
  • There are claims that hexane is immiscible in water but miscible in other hydrocarbons, suggesting it may be soluble in crude oil, which consists mainly of hydrocarbons.
  • Participants discuss the presence of sulfur in crude oil, with some stating it is an impurity and questioning its relevance to hexane's solubility.
  • One participant asserts that non-polar substances tend to dissolve in other non-polar substances, suggesting that hexane is likely soluble in crude oil.

Areas of Agreement / Disagreement

Participants express differing views on whether hexane is soluble in crude oil, with some supporting the idea of solubility based on hydrocarbon interactions, while others argue against it based on distillation principles. The discussion remains unresolved with multiple competing views.

Contextual Notes

There are limitations regarding the definitions of solubility and miscibility, as well as the specific composition of crude oil, which may affect the conclusions drawn. The discussion also highlights the complexity of interactions between different types of hydrocarbons and impurities.

soopo
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Homework Statement


Does hexane dissolve in Crude oil?

My attempt

I know it dissolves in fats and to some oils.
I am not sure whether it means crude oil too.
 
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Do you known what kind of compounds are present in crude oil? How they are relataed to hexane?
 
You might be fascinated to know that hexane is isolated from crude oil.
 
Borek said:
Do you known what kind of compounds are present in crude oil? How they are relataed to hexane?

I think that crude oil consists of old fossils which are in the liquid form.
For example, the marine fossils are in the liquid.
 
chemisttree said:
You might be fascinated to know that hexane is isolated from crude oil.

I found from Wikipedia that hexane is isolated from crude oil by distillation.

This means that the isolation process depends on the boiling points of the substances in the initial crude oil.
This also means that if hexane could dissolve in crude oil, you could not use distillation to separate the substances.
Therefore, I suggest that hexane cannot dissolve in crude oil.
 
Borek said:
What kind of mixtures can be separated by distillation?

Hydrocarbons such as alkanes, cycloalkanes and aromatic hydrocarbons.
 
So alcohols can't be separated? Nor ethers?

Do you know what 'miscible' means?
 
soopo said:
I think that crude oil consists of old fossils which are in the liquid form.
For example, the marine fossils are in the liquid.

I've never seen a fossil in crude oil.

This means that the isolation process depends on the boiling points of the substances in the initial crude oil.
This also means that if hexane could dissolve in crude oil, you could not use distillation to separate the substances.

You probably haven't ever seen crude oil before. It is a solution of a large variety of mostly hydrocarbons (some sulfur compounds and nitrogen-containing compounds as well). The key term is 'solution'. Miscibility is a prerequisite for 'solution' don't you agree?
 
  • #10
Borek said:
So alcohols can't be separated? Nor ethers?

Do you know what 'miscible' means?

Miscible means that two different solutions can mix together such as water and ethanol are miscible since they mix in all properties.

Hexane is a hydrocarbon. Crude oil consist a variety of different hydrocarbon chains.
I know that methane is a gas and the oil sources contain it.
The more carbon the hydrocarbon chain contain, the greater boiling point.
This suggests me that hexane is a liquid.

Wikipedia tells us that hexane is immiscible in water.
However, it is apparently miscible in other hydrocarbons.

Since crude oil does not only contain hydrocarbons at least initially, I suggest that hexane is soluble in hydrocarbons.

It is not apparently soluble in sulfur which crude has initially.
 
  • #11
You don't have to guess whether hexane is a liquid or not, it is much simpler to check. Or to remember which hydrocarbons are gaseous, which are liquid and which are solid at the room temperature.

How much sulfur in crude oil? Is it one of the main components, or just impurity?
 
  • #12
Borek said:
You don't have to guess whether hexane is a liquid or not, it is much simpler to check. Or to remember which hydrocarbons are gaseous, which are liquid and which are solid at the room temperature.

How much sulfur in crude oil? Is it one of the main components, or just impurity?

It is an impurity which needs to removed for environmental reasons at least from bensin.
Crude oil contains sulfur about 1%.

It is not one of the main components.
Hydrocarbons are the main components.
 
  • #13
soopo said:
It is not apparently soluble in sulfur which crude has initially.

soopo said:
Crude oil contains sulfur about 1%.

It is not one of the main components.

So is the hexane solubility in the sulfur relevant to the problem, or not?
 
  • #14
Borek said:
So is the hexane solubility in the sulfur relevant to the problem, or not?

It is not relevant to the problem, since it can be removed from crude oil.

It seems that pure crude oil consists only hydrocarbons.
We know that non-polars love non-polars.
Hexane seems to be soluble in crude oil.
 

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