How Can I Safely Remove Sticky Residue from an HCl Bottle?

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Discussion Overview

The discussion centers around the safe removal of sticky residue from an old bottle of 12 M hydrochloric acid (HCl). Participants explore various cleaning methods and the potential causes of the residue, including chemical interactions and improper storage conditions.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant suggests rinsing the bottle in water, noting that the white crystals near the spout could be amine chlorides, indicating improper storage with volatile amines.
  • Another participant proposes that the sticky residue might be leftover glue from a label, potentially affected by volatile vapors that caused discoloration.
  • A different viewpoint indicates that sticky substances are often greases and oils from vacuum pumps, recommending the use of hexanes followed by acetone for removal.

Areas of Agreement / Disagreement

Participants present multiple competing views on the nature of the sticky residue and the appropriate cleaning methods, with no consensus reached on a single solution.

Contextual Notes

Participants mention various potential causes for the residue, including chemical interactions and storage conditions, but do not resolve the specifics of the cleaning process or the exact nature of the residue.

mishima
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I found an old bottle of 12 M HCl that has a sticky residue on the outside of the bottle. It had a discoloring effect on blue fabric. How can I safely remove this?
 
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I guess that was a little vague. I'm asking how to clean the bottle, not the fabric.

The bottle was inside an acid cabinet, but not a bag alone. It had white crystals near the spout.
 
Have you tried rinsing the bottle in water? White crystals might be amine chlorides. This would indicate that sometime during the bottle's history it was improperly stored with volatile amines... usually ammonium hydroxide. Sticky residues can be anything. If the lab uses vacuum pumps and the exhaust from those pumps is not ventilated properly, you can get volatiles from experiments (bad ju ju!) and vacuum pump oil inside someplace like the cabinet beneath a vented hood where acids like this are sometimes stored. In my experience, sticky substances are usually greases and oils from a pump and are best removed with something like hexanes followed by acetone.

YMMV
 
Probably leftover glue left after the label was peeled off. Some volatile vapours might had stuck to it, causing that discoloration.
 

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