How do i determine which valence is being used (balancing equations)

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    Balancing equations
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Discussion Overview

The discussion revolves around the challenges of determining which valence state of a metal, particularly transition metals, is being used when balancing chemical equations. Participants explore methods for identifying the appropriate valence based on given reactants and the context of the compounds involved.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Homework-related

Main Points Raised

  • One participant expresses difficulty in identifying the valence of metals with multiple oxidation states when balancing equations.
  • Another participant provides an example using gold (Au), noting its multiple valences of +1, +2, and +3, and questions how to determine which is applicable in a given equation.
  • A participant mentions that polyatomic ions have a fixed valence, indicating that the complexity arises primarily with transition metals.
  • One contribution suggests that the valence can be inferred from the salts involved in the equation, using Au2(SO4)3 as an example to illustrate how the valence of gold must be +3 to balance the sulfate ions.
  • Another participant adds that if a metal is presented as a free element, its valence is 0, and otherwise, it should be determined based on the compound it is part of.

Areas of Agreement / Disagreement

Participants present multiple approaches to determining valence states, indicating that there is no single consensus on the method. Some methods are discussed, but uncertainty remains regarding the best approach for various scenarios.

Contextual Notes

Participants reference specific examples and external resources, but the discussion does not resolve the complexities involved in determining valences for transition metals in all contexts.

Who May Find This Useful

This discussion may be useful for students and educators involved in chemistry, particularly those focusing on balancing chemical equations and understanding oxidation states of metals.

supernova1203
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In balancing chemical equations, we are given let's say the reactants side of the equation and asked to find the products and balance if neccesary, if a metal(usually transition) has multiple valences, how do i know which of the valences is being used?

this has given me trouble to no end @_@
 
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for instance look at this, Au has a valence of +1, +2 and +3 so how would i know beforehand which valence they are using? This equation is already balanced and the work is done for us, but in case it isnt, how do i determine that?
 
here we go

I know the polyatomic ions have only 1 valence so that's not the problem, the sulphate has a valence of 2


This is a website i got off someone on these forums a few days ago, it shows what i am talking about, some of them have several valences..

http://chemistry.about.com/library/weekly/aa122002a.htm


hope you can see the attachment i have linked in this thread.
 

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You know the valence by looking at the salts shown. For instance, in Au2(SO4)3, the valence of the gold has to be +3 for each gold ion to balance the +2 of each of the 3 sulfate ions. The bromide salts are even easier.
 
pmsrw is correct. If they are giving it to you as a free metal the valence is 0. Otherwise you look at the compound it is in.
 

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