How do I find expectation values for a particle in an infinite well?

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SUMMARY

The discussion focuses on calculating expectation values for a particle in an infinite potential well defined by the potential V(x)=0 for -a/4 < x < 3a/4. The wavefunction is determined as ψ(x)=√(2/a)sin[nπ/a(x+a/4)]. The user successfully computes as a/4 but encounters difficulties with , leading to confusion over unit consistency in their calculations. The correct expression for is suggested to be a^2(7n^2π^2-24)/64n^2π^2, and the user inquires about the validity of calculating

as zero based on the time derivative of .

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  • Quantum mechanics fundamentals, specifically the concept of wavefunctions.
  • Integration techniques, including integration by parts.
  • Understanding of expectation values in quantum mechanics.
  • Familiarity with trigonometric identities and their application in integrals.
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  • Learn advanced integration techniques, particularly integration by parts in the context of quantum mechanics.
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I want to find <x> and ,<x^2>, <p>, and <p^2> of a particle in an infinite well where:
[tex]V(x)=0, \frac{-a}{4}<x<\frac{3a}{4}[/tex]

Using the usual method, I found the wavefunction to be:
[tex]\psi(x)=\sqrt{\frac{2}{a}}sin[\frac{n\pi}{a}(x+\frac{a}{4})][/tex]

I also found:
[tex]<x>=\frac{2}{a}\int_{\frac{-a}{4}}^{\frac{3a}{4}}xsin^2[\frac{n\pi}{a}(x+\frac{a}{4})]dx=\frac{a}{4}[/tex]

<x^2> is where I encounter the 1st problem. Here's my attempt:
[tex]<x^2>=\frac{2}{a}\int_{\frac{-a}{4}}^{\frac{3a}{4}}x^2sin^2[\frac{n\pi}{a}(x+\frac{a}{4})]dx[/tex]
Using by parts I let:
[tex]u=x^2[/tex]
[tex]du=2xdx[/tex]
[tex]dv=sin^2[\frac{n\pi}{a}(x+\frac{a}{4})]dx[/tex]
[tex]v=\frac{x}{2}-\frac{a}{2n\pi}sin[\frac{n\pi}{a}(x+\frac{a}{4})]cos[\frac{n\pi}{a}(x+\frac{a}{4})]=\frac{x}{2}-\frac{a}{4n\pi}sin[\frac{2n\pi}{a}(x+\frac{a}{4})][/tex]
(double angle formula used)

[tex]<x^2>=uv-\int vdu=\frac{2}{a}\left [ \left ((x^2)(\frac{x}{2}-\frac{a}{4n\pi}sin[\frac{2n\pi}{a}(x+\frac{a}{4})]) \right )_{\frac{-a}{4}}^{\frac{3a}{4}} -\int_{\frac{-a}{4}}^{\frac{3a}{4}}2x(\frac{x}{2}-\frac{a}{4n\pi}sin[\frac{2n\pi}{a}(x+\frac{a}{4})])dx\right ][/tex]
[tex]=\frac{2}{a}\left [ \frac{27a^3}{128}-\frac{-a^3}{128}-\int_{\frac{-a}{4}}^{\frac{3a}{4}}x^3dx+\frac{a}{4n\pi}\int_{\frac{-a}{4}}^{\frac{3a}{4}}2xsin[\frac{2n\pi}{a}(x+\frac{a}{4})])dx\right ][/tex]
[tex]=\frac{2}{a}\left [ \frac{7a^3}{32}-\frac{5a^4}{64}+\frac{a}{2n\pi}\left ( \frac{a^2}{4n^2\pi^2}sin[\frac{2n\pi}{a}(x+\frac{a}{4})])-\frac{a}{2n\pi}xcos[\frac{2n\pi}{a}(x+\frac{a}{4})])\right )_{\frac{-a}{4}}^{\frac{3a}{4}}\right ][/tex]
Sine term vanishes at both limits while cosine term as 1 at both limits:
[tex]=\frac{2}{a}\left [ \frac{7a^3}{32}-\frac{5a^4}{64}+\frac{a}{2n\pi}\left ( \frac{-3a^2}{8n\pi}+\frac{a^2}{8n\pi} \right )\right ]=\frac{7a^2}{16}-\frac{a^2}{4n^2\pi^2}-\frac{5a^3}{32}=\frac{a^2(7n^2\pi^2-4)}{16n^2\pi^2}-\frac{5a^3}{32}[/tex]

This is obviously wrong since the units don't add up/ How can there be a^2 and a^3 at the same time? I spend hours checking and still can't find my mistake.

I plug the equation into a graphic calculator, I think the answer should be:
[tex]\frac{a^2(7n^2\pi^2-24)}{64n^2\pi^2}[/tex]


Now, for <p>, can I just have:
[tex]<p>=m\frac{d<x>}{dt}=m\frac{d}{dt}\frac{a}{4}=0[/tex]
Is this alright or do I have to plug the operator in and integrate?
 
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I think I spot your mistake: from the line in <x^2>=... in the integral you pass from
[itex]\int_{\frac{-a}{4}}^{\frac{3a}{4}}2x(\frac{x}{2})dx[/itex] in the firs line to [itex]\int_{\frac{-a}{4}}^{\frac{3a}{4}}x^3dx[/itex] in the second one
 

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