How do we get the expectation value formula?

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Discussion Overview

The discussion centers around the derivation and understanding of the expectation value formula in quantum mechanics, specifically the expression involving the wave function and its complex conjugate. Participants explore the theoretical foundations and connections to observations in physics, as well as seek resources for further reading.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested
  • Homework-related

Main Points Raised

  • One participant presents the expectation value formula <x> = ∫ complex ψ x ψ dx and asks for clarification on its derivation and the role of the complex wave function.
  • Another participant suggests that the formula is constructed to match observational results, mentioning theoretical arguments that may not encompass all aspects.
  • There is a discussion about whether the complex conjugate must be used, with some asserting that it is not necessary when multiplying complex numbers.
  • Participants discuss the Schrödinger equation's derivation from basic assumptions about physical states and time evolution, emphasizing its alignment with observations.
  • One participant requests recommendations for resources on the derivation of the Schrödinger equation.
  • Another participant draws an analogy between the expectation value in quantum mechanics and probability theory, referencing the Born rule and the expectation value for continuous random variables.
  • Links to various resources, including chapters from Ballentine's book and other papers, are shared, with differing opinions on the quality of these references.

Areas of Agreement / Disagreement

Participants express varying views on the necessity of the complex conjugate in the expectation value formula and the derivation of the Schrödinger equation. There is no consensus on the best resources for learning about these topics, as opinions on the quality of different texts vary.

Contextual Notes

Some discussions involve assumptions about the mathematical foundations of quantum mechanics and the relationship between physical states and observations, which may not be fully articulated or agreed upon.

Who May Find This Useful

This discussion may be of interest to students and enthusiasts of quantum mechanics, particularly those seeking to understand the expectation value formula and its theoretical underpinnings.

Outrageous
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<x>= ∫ complex ψ x ψ dx
How do we get this formula? And why must the complex ψ must be placed in front?
Please guide or any link to help,not really understand this makes me difficult to start in quantum mechanics.
Your help is really appreciated. Pls
 
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How do we get this formula?
Observation, it fits to the measurement results (there are also some theoretical arguments that it cannot be everything, but those are details. The main point is: the theory was constructed to match observations).

And why must the complex ψ must be placed in front?
Do you mean complex conjugation? It does not have to, you multiply complex numbers here.
 
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mfb said:
Observation, it fits to the measurement results (there are also some theoretical arguments that it cannot be everything, but those are details. The main point is: the theory was constructed to match observations).

Do you mean complex conjugation? It does not have to, you multiply complex numbers here.

Thanks. One more to ask, even Schrödinger equation is also constructed to match observation?
 
Outrageous said:
Thanks. One more to ask, even Schrödinger equation is also constructed to match observation?

All of physics is - observation, plus mathematical consistency (and a certain degree of "taste").

You can derive the Schrödinger equation from some more basic assumptions: that physical states are elements in a vector space, and that time evolution acts on that vector space as a unitary transformation. Then given the relation between energy and time in classical physics, the Schrödinger equation follows.
 
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kaplan said:
All of physics is - observation, plus mathematical consistency (and a certain degree of "taste").

You can derive the Schrödinger equation from some more basic assumptions: that physical states are elements in a vector space, and that time evolution acts on that vector space as a unitary transformation. Then given the relation between energy and time in classical physics, the Schrödinger equation follows.

Thanks~ Do you have any link or book recommended for the derivation mentioned?
 
Chapter 3 of Ballentine is OK. There are probably better references (overall that book isn't very good), but that's the only one I can think of off the top of my head.
 
kaplan said:
Chapter 3 of Ballentine is OK. There are probably better references (overall that book isn't very good), but that's the only one I can think of off the top of my head.

Thanks, I try to check it out^^
 
How do we get this formula?
There is also an analogy to probability theory, based on the Born rule that ##\psi^* \psi## is a probability distribution. The expression of the quantum-mechanical expectation value
$$
\langle \hat{A} \rangle = \int \psi^* \hat{A} \psi d\tau
$$
is analogous to the expectation value for a continuous random variable
$$
E[X] = \int_{-\infty}^{\infty} x f(x) dx
$$
especially in the case you mention where you want ##\langle x \rangle## for ##\psi(x)##.
 
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You might be interested in checking out Gleason's Theorem:
http://kof.physto.se/theses/helena-master.pdf

For the basis of Schrödinger's Equation see (as has already been mentioned) Chapter 3 - Ballentine - Quantum Mechanics - A Modern Development:
http://www-dft.ts.infn.it/~resta/fismat/ballentine.pdf

Believe it or not it actually follows from symmetry - strange but true.

Actually so does Classical Mechanics for that matter - and how it is connected to QM is very interesting - see Landau - Mechanics for example.

In fact this is one of the very deep revelations of physics and well worth becoming acquainted with:
http://www.pnas.org/content/93/25/14256.full.pdf

All books on QM suck in their own unique way and its a matter of taste what approach you take to and book you gravitate towards. I personally love Ballentine - to me it was a revelatory book on QM - but opinions vary. Check it out for yourself and make up your own mind.

Thanks
Bill
 
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