Quasar:
Don't you need to start with a choice of metric so that you can select the infimum over the collection of all curves? i.e., in order to define d_L:=inf{d(x,y)} over all rectifiable curves joining x and y, we must start with a notion of d .
To add to your and Mathwonk's example, (example is also given in above Wikipedia link), the circle with the subspace metric does not generate an intrinsic metric, since the Euclidean distance between any x,y on the circle does not equal the arc-length distance, i.e., there are no arc-length paths of length equal to the Euclidean length between points, say, for (-1,0) and (1,0), there are no arc-length paths of length 2 in S^1 between those two points.