A Po(Lambda) process models a process whose jumps (arrivals) occur at rate Lambda - probability of a jump in time dt is Lambda * dt to highest order in dt (http://en.wikipedia.org/wiki/Poisson_process" .) You could use the fact that the distance between these jumps are independent and exponentially distributed. So the time to the n'th jump (n'th claim) is the sum of n independent exponential r.v.s, which is a chi(2n)-squared distribution.
You could also work out the result for n = 1, and then extend to larger n. If t(n) is the time of the n'th arrival of X & Y combined, then look at the process Z(n) = X(t(n))-Y(t(n)). You can use the memorylessness property to show that this will be a random walk, and is given by the binomial distribution for each n. To say that the first n arrivals of X occur before the first n arrivals of Y is equivalent to Z(2n-1)>=0, which you can then get from the binomial distribution.
Do you know the result for n=1?