How Do You Determine Which Reaction to Flip in a Voltaic Cell?

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SUMMARY

The discussion focuses on determining which half-reaction to flip in a voltaic cell involving manganese (Mn) and cadmium (Cd) half-cells. The initial cell potential is +0.768 V, with Mn/Mn2+ having a standard reduction potential of -1.18 V and Cd/Cd2+ at -0.40 V. To calculate the concentration of Cd2+ using the Nernst equation, one must recognize that the half-cell with the more negative potential (Mn) is oxidized, while the other (Cd) is reduced. The equation E(cell) = E(oxidation) + E(reduction) necessitates flipping the sign of the potential for the oxidized half-reaction.

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Homework Statement



A voltaic cell at 25oC consists of Mn/Mn2+ and Cd/Cd2+ half-cells with an initial cell potential of +0.768 V. The [Mn2+] concentration is 0.500 M. Use the Nernst equation to calculate the [Cd2+] concentration in the Cd/Cd2+ half-cell.
Cd+2(aq) + 2e- = Cd(s) . . . . . Eo = -0.40 V
Mn+2(aq) + 2e- = Mn(s) . . . . . Eo = -1.18 V


Homework Equations



Ecell = E(standard) cell - (RT/nF)ln Q

The Attempt at a Solution



I was just wondering how do we know which reaction above, we need to flip and how do we determine which metal is oxidized and reduced in cells like this? Is it that the half-cell woth the more negative potential is more redilly reduced, thus that's the one you flip, to create the cell?
I know how to use the nerst equation and find concentration, but am having trouble with Enot Cell because i don't know which eqn to flip.
 
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What and why do you want to flip?

All you need is

EMn/Mn2+ = ECd/Cd2+
 


How is EMn/Mn2+ = ECd/Cd2+ ?
EMn/Mn2+ = -1. 18 and ECd/Cd2+= -0.40

The potential given is the E(reduction), if we use the equation E(cell) = E(oxidation) + E(reduction). Then we need to change the sign of one of the potentials to get that reactions E(oxidation).
 

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