How do you find the gauche number?

  • Thread starter Thread starter noxflos
  • Start date Start date
Click For Summary
SUMMARY

The discussion focuses on determining the gauche number in staggered conformations, specifically in 2,3-dimethylbutane. The term "gauche number" refers to the count of gauche interactions present in a molecular structure. In the case of 2,3-dimethylbutane, there are two gauche interactions identified among the four methyl groups. The discussion also touches on the importance of visualizing chair conformations, particularly in cyclohexane, to accurately assess gauche interactions.

PREREQUISITES
  • Understanding of molecular conformations
  • Familiarity with staggered and eclipsed arrangements
  • Knowledge of cyclohexane chair conformations
  • Basic concepts of steric interactions in organic chemistry
NEXT STEPS
  • Study the concept of gauche interactions in various molecular structures
  • Learn to draw and analyze chair conformations of cyclohexane
  • Explore the impact of steric hindrance on molecular stability
  • Investigate the role of conformational analysis in organic synthesis
USEFUL FOR

Chemistry students, organic chemists, and anyone interested in molecular conformations and steric interactions in organic compounds.

noxflos
Messages
10
Reaction score
0
In a staggered confirmation of 2,3-dimeythlbutane, how do you find the gauche number? For that matter, how do you find any gauche number for a chair confirmation? I'm having a hard time understanding it through my book's description.
 
Chemistry news on Phys.org
Hmm, I'm not familiar with the terminology of "gauche number." Perhaps it just means the number of gauche interactions present? Yeah, without drawing a lot of pictures and looking at the bonds this way and that it's tough to see these conformations most of the time. In staggered 2,3-dimethylbutane I see 2 total interactions that I would call gauche. (4 methyl groups to consider, 2 pairs in gauche). Maybe that's the gauche number (2)?

For any chair conformation? I suppose you mean of cyclohexyl rings, I dunno?

You just have to draw the picture out from the perspective that you can see where the interactions for whatever you're talking about are "gauche."
 
Thank you for your help. I met with my professor and he explained it...it was # of gauche interactions. Again thanks for your help.
 

Similar threads

  • · Replies 47 ·
2
Replies
47
Views
4K
  • · Replies 13 ·
Replies
13
Views
2K
  • · Replies 3 ·
Replies
3
Views
715
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 9 ·
Replies
9
Views
3K
  • · Replies 7 ·
Replies
7
Views
2K
  • · Replies 10 ·
Replies
10
Views
3K
  • · Replies 11 ·
Replies
11
Views
2K
  • · Replies 6 ·
Replies
6
Views
804
  • · Replies 6 ·
Replies
6
Views
2K