How do you find the number of hydrogen bonds between molecules?

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SUMMARY

The discussion focuses on determining the number of hydrogen bonds formed between isopropyl alcohol (C3H8O) molecules. It is established that each isopropyl alcohol molecule can act as a hydrogen bond donor through its hydroxyl (OH) group and can accept hydrogen bonds from two other molecules due to the presence of two lone pairs on the oxygen atom. Therefore, one molecule of isopropyl alcohol can form a total of three hydrogen bonds with other isopropyl alcohol molecules. This contrasts with water, which can form four hydrogen bonds per molecule.

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  • Understanding of hydrogen bonding principles
  • Familiarity with molecular structures, specifically isopropyl alcohol and ethanol
  • Knowledge of lone pairs and their role in bonding
  • Basic chemistry concepts related to intermolecular forces
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Chemistry students, researchers in molecular biology, and professionals in chemical engineering who are interested in the properties and interactions of alcohols and their hydrogen bonding behavior.

MeMoses
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Hey, I'm wondering how you figure out the number of hydrogen bonds acting between molecules. I know each water molecule supposedly makes 4 hydrogen bonds with other water molecules through my reading, but I want to know how many for isopropyl alcohol, which has only one OH group. I know its less than water based on the properties of the two, but that's it. I think it may be either 1 or 3 but I am not sure how to figure this out. Any help would be appreciated.
 
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If it were three, what hydrogens on isopropyl alcohol would be involved in hydrogen bonding?
 
Hydrongens in the OH group of other molecules would be used. You could have two H from other molecules bond to the O of the original molecule and then the H (of the original molecule) bonds to the O of another. If that is allowed
 
If its H-bonding with only one species present (IE neat EtOH) just look at the molecule and find the H-bond donor(s) and H-bond acceptor(s). It can get much more complicated if there are more than one species present (IE such as a solution or a mixture etc) because other effects, such as sterics and such, may play a role as to what H-bond with what

So for EtOH, we have CH3CH2OH. One H-bond donor, but two lone pairs on the Oxygen can accept 2 H-bonds (from two other molecules of EtOH). So 1 molecule of EtOH can H-bond to three other EtOH molecules.
 

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