How Do You Normalize and Calculate Expectation Values in Quantum Mechanics?

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SUMMARY

The discussion focuses on normalizing a quantum mechanical wave function and calculating expectation values for a particle in one dimension. The wave function is given as ψ(x) = Ae^{−λ|x|}, where A and λ are positive constants. The normalization was achieved by evaluating the integral ∫_{-∞}^{∞} A²e^{-2λ|x|}dx, resulting in A = √λ. Expectation values ⟨x⟩ and ⟨x²⟩ were computed using the equations ⟨ψ|ψ⟩ = 1 and ⟨A⟩ = ⟨ψ|A|ψ⟩, with the final result for ⟨x⟩ being 0, while the calculation for ⟨x²⟩ required integration by parts.

PREREQUISITES
  • Understanding of quantum mechanics concepts, specifically wave functions and expectation values.
  • Familiarity with integration techniques, particularly integration by parts.
  • Knowledge of the properties of exponential functions and absolute values in integrals.
  • Experience with mathematical software like Mathematica for complex integrals.
NEXT STEPS
  • Learn advanced integration techniques, including multiple applications of integration by parts.
  • Study the normalization of wave functions in various quantum states.
  • Explore the use of integral tables for solving complex integrals in quantum mechanics.
  • Investigate the differences between using software tools like Mathematica and manual calculations in quantum mechanics.
USEFUL FOR

Students and professionals in quantum mechanics, physicists working on wave function analysis, and anyone interested in mastering expectation value calculations in quantum systems.

richyw
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Homework Statement



A particle moving in one dimensions is in the state |\psi\rangle with position-space wave function \psi(x) = Ae^{−\lambda|x|} where A, λ are positive real constants.

a)Normalize the wavefunction.

b)Determine the expectation values of x and x^2

Homework Equations



\langle\psi | \psi\rangle=1\]
\langle \hat{A}\rangle = \langle \psi |\hat{A}|\psi \rangle

The Attempt at a Solution



I used the first equation to normalize the wave function by doing
\int^{\infty}_{-\infty}A^2e^{-2\lambda |x|}dx. I had to do this by splitting the integral into two parts to get rid of the absolute value. I ended up with A=\sqrt{\lambda}

Then I got \langle x \rangle by doing

\int^{\infty}_{-\infty}\lambda x e^{-2\lambda |x|}dxwhich I had to use an integration by parts (one question I have is if there is an "easy" way to do IBP without listing out all of the variable changes and stuff. it's very time consuming. Anyways the answer I got is 0.

For x^2I am trying to just plug it into the formula. The problem is I cannot seem to integrate this properly. I can plug it into mathematica but I cannot seem to work out the integral!
 
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Surely A = Realthingy times e(i alpha), alpha is an arbitrary realthingy.

The method you used to compute the integral in <x> must work for <x^2> as well. You need to do partial integration not once, but twice.
 
Do you need to use Mathematica? Just use integral table or or solve it as mentioned above. In all my QM courses, we never used Maple, or Mathematica.
 

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